2'-benzyloxymethyl-6'-methoxy-2,4',6-tris(methoxymethoxy)-3,5-dichloro-4-methylbenzophenone

Base Information

Chemical Name:2'-benzyloxymethyl-6'-methoxy-2,4',6-tris(methoxymethoxy)-3,5-dichloro-4-methylbenzophenone
CAS No.:261958-59-2
Molecular Formula:C₂₉H₃₂Cl₂O₉
Molecular Weight:595.474
Hs Code.:

Synonyms:2'-benzyloxymethyl-6'-methoxy-2,4',6-tris(methoxymethoxy)-3,5-dichloro-4-methylbenzophenone

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2'-benzyloxymethyl-6'-methoxy-2,4',6-tris(methoxymethoxy)-3,5-dichloro-4-methylbenzophenone

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Technology Process of 2'-benzyloxymethyl-6'-methoxy-2,4',6-tris(methoxymethoxy)-3,5-dichloro-4-methylbenzophenone

There total 15 articles about 2'-benzyloxymethyl-6'-methoxy-2,4',6-tris(methoxymethoxy)-3,5-dichloro-4-methylbenzophenone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 261958-58-1
4-{[2-benzyloxymethyl-6-methoxy-4-(methoxymethoxy)phenyl]hydroxymethyl}-3,5-bis(methoxymethoxy)-2,6-dichlorotoluene

: 261958-59-2
2'-benzyloxymethyl-6'-methoxy-2,4',6-tris(methoxymethoxy)-3,5-dichloro-4-methylbenzophenone

Guidance literature:: With Dess-Martin periodane; In dichloromethane; at 20 ℃;
DOI:10.1016/S0040-4039(99)02005-5

Reference yield:

: 2150-44-9
1-carbomethoxy-3,5-dihydroxybenzene

: 261958-59-2
2'-benzyloxymethyl-6'-methoxy-2,4',6-tris(methoxymethoxy)-3,5-dichloro-4-methylbenzophenone

Guidance literature:: Multi-step reaction with 10 steps

1: 87 percent / DIPEA / CH₂Cl₂ / 5 h / 0 - 20 °C

2: 98 percent / LiAlH₄ / diethyl ether / 2 h / 0 - 20 °C

3: 93 percent / N-bromosuccinimide / dimethylformamide / 2 h / 0 °C

4: 95 percent / NaH / dimethylformamide / 1 h / 0 - 20 °C

5: 95 percent / n-BuLi / hexane; diethyl ether / 3 h / -78 - 20 °C

6: 94 percent / aq. HCl / tetrahydrofuran / 2 h / 20 °C

7: 72 percent / K₂CO₃ / acetone / 1 h / 20 °C

8: 90 percent / Cs₂CO₃ / dimethylformamide / 1 h / 20 °C

9: 86 percent / n-BuLi / tetrahydrofuran; hexane / 3.25 h / -78 - 20 °C

10: 98 percent / Dess-Martin periodinane / CH₂Cl₂ / 0.75 h / 20 °C

With hydrogenchloride; N-Bromosuccinimide; lithium aluminium tetrahydride; n-butyllithium; sodium hydride; potassium carbonate; caesium carbonate; Dess-Martin periodane; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; diethyl ether; hexane; dichloromethane; N,N-dimethyl-formamide; acetone; 10: Dess-Martin oxidation;
DOI:10.1016/S0040-4020(01)01250-9

Reference yield:

: 63992-61-0
4,6-dichloro-5-methylresorcinol

: 261958-59-2
2'-benzyloxymethyl-6'-methoxy-2,4',6-tris(methoxymethoxy)-3,5-dichloro-4-methylbenzophenone

Guidance literature:: Multi-step reaction with 4 steps

1: 88 percent / Br₂ / CH₂Cl₂; dimethylformamide / 3 h / 20 °C

2: 100 percent / DIPEA / CH₂Cl₂ / 1 h / 20 °C

3: 86 percent / n-BuLi / tetrahydrofuran; hexane / 3.25 h / -78 - 20 °C

4: 98 percent / Dess-Martin periodinane / CH₂Cl₂ / 0.75 h / 20 °C

With n-butyllithium; bromine; Dess-Martin periodane; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; hexane; dichloromethane; N,N-dimethyl-formamide; 4: Dess-Martin oxidation;
DOI:10.1016/S0040-4020(01)01250-9