[Cu(bis[2-(diphenylphosphino)phenyl]ether)(CH₃CN)₂]BF₄

Base Information

• Chemical Name: [Cu(bis[2-(diphenylphosphino)phenyl]ether)(CH₃CN)₂]BF₄
• CAS No.: 1254575-15-9
• Molecular Formula: BF₄*C₄₀H₃₄CuN₂OP₂
• Molecular Weight: 771.021
• Mol file: 1254575-15-9.mol

Synonyms:[Cu(bis[2-(diphenylphosphino)phenyl]ether)(CH₃CN)₂]BF₄

Chemical Property of [Cu(bis[2-(diphenylphosphino)phenyl]ether)(CH₃CN)₂]BF₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Cu(bis[2-(diphenylphosphino)phenyl]ether)(CH₃CN)₂]BF₄

There total 1 articles about [Cu(bis[2-(diphenylphosphino)phenyl]ether)(CH₃CN)₂]BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

tetrakis(acetonitrile)copper(I)tetrafluoroborate + bis[2-(diphenylphosphino)phenyl] ether (166330-10-5) → [Cu(bis[2-(diphenylphosphino)phenyl]ether)(CH3CN)2]BF4 (1254575-15-9)

Guidance literature:

In dichloromethane; at 20 ℃; for 8h; Inert atmosphere;

DOI:10.1002/anie.201404186

Reference yield: 87.0%

[Cu(bis[2-(diphenylphosphino)phenyl]ether)(CH3CN)2]BF4 (1254575-15-9) + 4,4'-bis(ethoxycarbonyl)-2,2'-bipyridine (1762-42-1) → [Cu(bis(2-(diphenylphosphanyl)phenyl) ether)(4,4'-di(CO2Et)-2,2'-bipyridine)][BF4] (1254575-01-3)

Guidance literature:

In acetone; Cu complex and ligand stirred in acetone at room temp. for 3 h; solvent removed under reduced pressure; pptd. by addition of i-PrOH overnight; elem. anal.;

DOI:10.1039/c0dt00190b

Reference yield: 79.7%

[Cu(bis[2-(diphenylphosphino)phenyl]ether)(CH3CN)2]BF4 (1254575-15-9) + para-bis(5’-(6’‘-methyl-pyrid-2’‘-yl)1H-1,2,3-triazol-4’-yl)benzene → C94H74Cu2N8O2P4(2+)*2BF4(1-)

Guidance literature:

for 4h;

DOI:10.1016/j.jorganchem.2018.07.013

upstream raw materials:

bis[2-(diphenylphosphino)phenyl] ether

Downstream raw materials:

[Cu(bis(2-(diphenylphosphanyl)phenyl) ether)(4,4'-di(CO₂Et)-2,2'-bipyridine)][BF₄]

[Cu(I)(bis[2-(diphenylphosphino)phenyl]ether)(4,4′,6,6′-tetramethyl-2,2′-bipyridyl)][BF₄]

[Cu(bis(2-(diphenylphosphanyl)phenyl) ether)(4,4',6,6'-tetracarboxy-2,2'-bipyridine)][BF₄]

[Cu(bis(2-(diphenylphosphanyl)phenyl) ether)(4,4'-dicarboxy-2,2'-bipyridine)][BF₄]