caesium heptafluoroxenonate (VI)

Base Information

• Chemical Name: caesium heptafluoroxenonate (VI)
• CAS No.: 19033-04-6
• Molecular Formula: Cs*F₇Xe
• Molecular Weight: 397.184

Synonyms:caesium heptafluoroxenonate (VI)

Chemical Property of caesium heptafluoroxenonate (VI)

Chemical Property:

Purity/Quality:

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Technology Process of caesium heptafluoroxenonate (VI)

There total 2 articles about caesium heptafluoroxenonate (VI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

caesium nitrate + xenon hexafluoride (13693-09-9) → xenon oxide tetrafluoride (13774-85-1) + caesium fluoride * xenon oxide tetrafluoride (12191-01-4) + caesium heptafluoroxenonate (VI) (19033-04-6) + Cs(1+)*XeO2F3(1-)=CsXeO2F3 (65014-03-1) + nitrylfluoride (10022-50-1)

Guidance literature:

In neat (no solvent); addn. of excess of CsNO3 to XeF6, heating (54°C, 16 h), cooling (-196°C, sepn. of volatile (fractional condensation, traps -78 (XeOF4) and -196.degre.C (FNO3)); further products; sepn. of solid (CsXeO2F3, CsXeF7 and XeO2F2); vibrational spectroscopy;

Reference yield:

caesium nitrate + xenon hexafluoride (13693-09-9) → xenon oxide tetrafluoride (13774-85-1) + caesium heptafluoroxenonate (VI) (19033-04-6) + nitrylfluoride (10022-50-1)

Guidance literature:

With NaF; In neat (no solvent); addn. of excess of XeF6 to CsNO3 (vac., -196°C), heating (56°C, 4 h), cooling (-196°C), sepn. of volatile (fractional condesation, traps -78 and -196°C), sepn. of XeOF4 (complexing of XeF6 with NaF, 70°C, 2 h); sepn. of solid; IR and Raman spectroscopy;

Reference yield:

caesium heptafluoroxenonate (VI) (19033-04-6) → xenon hexafluoride (13693-09-9) + dicaesium octafluoroxenonate (VI)

Guidance literature:

In neat (no solvent); on thermal decompn.; decompn. is starting above 50°C and ending at about 280°C;;

DOI:10.1016/0022-1902(66)80380-9

upstream raw materials:

xenon hexafluoride

Downstream raw materials:

xenon hexafluoride

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