Technology Process of 1D-2,4,5,6-tetra-O-benzyl-3-deoxy-1-O-p-methoxybenzyl-myo-inositol
There total 1 articles about 1D-2,4,5,6-tetra-O-benzyl-3-deoxy-1-O-p-methoxybenzyl-myo-inositol which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 2 steps
1: 66 percent / NaBH4; BF3*OEt2 / 1,2-dimethoxy-ethane / 2 h / 20 °C
2: 95 percent / NaH / dimethylformamide / 1.5 h / 20 °C
With
sodium tetrahydroborate; boron trifluoride diethyl etherate; sodium hydride;
In
1,2-dimethoxyethane; N,N-dimethyl-formamide;
DOI:10.1039/b411021h
- Guidance literature:
-
With
2,3-dicyano-5,6-dichloro-p-benzoquinone;
In
dichloromethane;
at 20 ℃;
for 2h;
DOI:10.1039/b411021h
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 85 percent / aq. DDQ / CH2Cl2 / 2 h / 20 °C
2: 2,2,6,6-tetramethylpiperidine / CH2Cl2 / 1 h / 20 °C
3: 4 Angstroem molecular sieves; 5-phenyl-1H-tetrazole / CH2Cl2 / 1.5 h / 0 - 20 °C
4: t-BuOOH / CH2Cl2; hexane / 1 h / 0 °C
5: 79 mg / H2 / Pd/C / 2-methyl-propan-2-ol / 18 h / 7500.6 Torr
With
2,2,6,6-tetramethyl-piperidine; tert.-butylhydroperoxide; 5-Phenyl-1H-tetrazole; 4 A molecular sieve; hydrogen; 2,3-dicyano-5,6-dichloro-p-benzoquinone;
palladium on activated charcoal;
In
hexane; dichloromethane; tert-butyl alcohol;
DOI:10.1039/b411021h
