(R)-benzyl 2-carboxymethylphenyl sulfoxide

Base Information

Chemical Name:(R)-benzyl 2-carboxymethylphenyl sulfoxide
CAS No.:1207457-51-9
Molecular Formula:C₁₅H₁₄O₃S
Molecular Weight:274.34
Hs Code.:

Synonyms:(R)-benzyl 2-carboxymethylphenyl sulfoxide

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Chemical Property of (R)-benzyl 2-carboxymethylphenyl sulfoxide

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Technology Process of (R)-benzyl 2-carboxymethylphenyl sulfoxide

There total 4 articles about (R)-benzyl 2-carboxymethylphenyl sulfoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 58435-43-1
2-methoxycarbonyl-1-benzylthiobenzene

: 1207457-51-9
(R)-benzyl 2-carboxymethylphenyl sulfoxide

Guidance literature:: With titanium(IV) isopropylate; tert.-butylhydroperoxide; di-tert-butyl peroxide; (S,S)-hydrobenzoin; In hexane; water; at 20 ℃; for 48h; optical yield given as %ee; enantioselective reaction;
DOI:10.1002/chem.200902110

Reference yield:

: 4892-02-8
Methyl thiosalicylate

: 1207457-51-9
(R)-benzyl 2-carboxymethylphenyl sulfoxide

: C₁₅H₁₄O₃S

Guidance literature:: Multi-step reaction with 2 steps

1.1: potassium carbonate / N,N-dimethyl-formamide / Reflux

2.1: 3-chloro-benzenecarboperoxoic acid / methanol

2.2: Chiralpak IC column / Resolution of racemate

With potassium carbonate; 3-chloro-benzenecarboperoxoic acid; In methanol; N,N-dimethyl-formamide;
DOI:10.1080/14756366.2019.1651315

Reference yield:

: 100-39-0
benzyl bromide

: 1207457-51-9
(R)-benzyl 2-carboxymethylphenyl sulfoxide

: C₁₅H₁₄O₃S

Guidance literature:: Multi-step reaction with 2 steps

1.1: potassium carbonate / N,N-dimethyl-formamide / Reflux

2.1: 3-chloro-benzenecarboperoxoic acid / methanol

2.2: Chiralpak IC column / Resolution of racemate

With potassium carbonate; 3-chloro-benzenecarboperoxoic acid; In methanol; N,N-dimethyl-formamide;
DOI:10.1080/14756366.2019.1651315