[Cr(cyclopentadienyl)((xylyl)NC(Me)CHC(Me)N(xylyl))Cl]

Base Information

• Chemical Name: [Cr(cyclopentadienyl)((xylyl)NC(Me)CHC(Me)N(xylyl))Cl]
• CAS No.: 1198298-27-9
• Molecular Formula: C₂₆H₃₀ClCrN₂
• Molecular Weight: 457.987

Synonyms:[Cr(cyclopentadienyl)((xylyl)NC(Me)CHC(Me)N(xylyl))Cl]

Chemical Property of [Cr(cyclopentadienyl)((xylyl)NC(Me)CHC(Me)N(xylyl))Cl]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Cr(cyclopentadienyl)((xylyl)NC(Me)CHC(Me)N(xylyl))Cl]

There total 11 articles about [Cr(cyclopentadienyl)((xylyl)NC(Me)CHC(Me)N(xylyl))Cl] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

2-((2,4,6-trimethylphenyl)amino)-4-((2,4,6-trimethylphenyl)imino)-2-pentene (368891-67-2) + chromium(III) chloride (10025-73-7,16284-59-6) + sodium cyclopentadienide → [Cr(cyclopentadienyl)((xylyl)NC(Me)CHC(Me)N(xylyl))Cl] (1198298-27-9)

Guidance literature:

In tetrahydrofuran; (N2); using Schlenk techniques; addn. of BuLi to soln. (Mes)NHCMeCHCMeN(Mes)/THF at 0°C; warming to room temp.; stirring for 1 h; cannulating to suspn. of CrCl3/THF; stirring at room temp. overnight; addn. of NaCp; stirring overnight at room temp; evapn. of solvent in vac., extn. with hexanes/CH2Cl2 mixt. (3:1), filtration, rinsing with hexanes; concn., cooling to -20°C; crystn. forseveral days; elem. anal.;

DOI:10.1021/om900869p

Reference yield:

(2,6-C6H3Me2)NHC(Me)CHC(Me)N(2,6-C6H3Me2) + chromium(III) chloride (10025-73-7,16284-59-6) + sodium cyclopentadienide → [Cr(cyclopentadienyl)((xylyl)NC(Me)CHC(Me)N(xylyl))Cl] (1198298-27-9)

Guidance literature:

With n-BuLi; In tetrahydrofuran; hexane; under N2; n-BuLi in hexanes added dropwise with stirring to soln. of ligand in THF (0°C); warmed to room temp. (40 min); added to suspn. of CrCl3 in THF; stirred at room temp. overnight; NaC5H5 in THF added; stirred at room temp. overnight; solvent removed in vac.; extd. with hexanes, Et2O and CH2Cl2; filtered through Celite; rinsed with hexanes; concd.; crystd. at -20°C;

DOI:10.1021/om900788c

Reference yield:

2-chloro-propionic acid methyl ester (17639-93-9) + CpCr[(XylNCMe)2CH] (1065614-63-2) → [Cr(cyclopentadienyl)((xylyl)NC(Me)CHC(Me)N(xylyl))Cl] (1198298-27-9)

Guidance literature:

In tetrahydrofuran; (Ar or N2); using Schlenk techniques; treatment of CpCr(nacnacXyl,Xyl) with 0.5 equiv. of methyl 2-chloropropionate in THF at room temp.; monitoring by UV;

DOI:10.1021/om1002649

upstream raw materials:

2-((2,4,6-trimethylphenyl)amino)-4-((2,4,6-trimethylphenyl)imino)-2-pentene

chromium(III) chloride

Chloromethyl pivalate

CpCr[(XylNCMe)₂CH]

Downstream raw materials:

[Cr(cyclopentadienyl)((xylyl)NC(Me)CHC(Me)N(xylyl))(tosylato)]

CpCr[(XylNCMe)2CH](CH₃)

CpCr[(2,6-Me₂C₆H₃NCMe)2CH](CH₂CHMe₂)

CpCr[(2,6-Me₂C₆H₃NCMe)2CH](CH₂Ph)

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 1198298-27-9 [Cr(cyclopentadienyl)((xylyl)NC(Me)CHC(Me)N(xylyl))Cl]

Send

Send

Metric Ton KG G Pound L ML

Send

Send