(2E,6E)-8-(benzyloxy)-6-methyl-2-<(trimethylsilyl)methyl>-2,6-octadienyl methanesulfonate

Base Information

Chemical Name:(2E,6E)-8-(benzyloxy)-6-methyl-2-<(trimethylsilyl)methyl>-2,6-octadienyl methanesulfonate
CAS No.:142720-34-1
Molecular Formula:C₂₁H₃₄O₄SSi
Molecular Weight:410.65
Hs Code.:

Synonyms:(2E,6E)-8-(benzyloxy)-6-methyl-2-<(trimethylsilyl)methyl>-2,6-octadienyl methanesulfonate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2E,6E)-8-(benzyloxy)-6-methyl-2-<(trimethylsilyl)methyl>-2,6-octadienyl methanesulfonate

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Technology Process of (2E,6E)-8-(benzyloxy)-6-methyl-2-<(trimethylsilyl)methyl>-2,6-octadienyl methanesulfonate

There total 3 articles about (2E,6E)-8-(benzyloxy)-6-methyl-2-<(trimethylsilyl)methyl>-2,6-octadienyl methanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 124-63-0
methanesulfonyl chloride

: 142720-32-9
(2E,6E)-8-(benzyloxy)-6-methyl-2-<(trimethylsilyl)methyl>-2,6-octadien-1-ol

: 142720-34-1
(2E,6E)-8-(benzyloxy)-6-methyl-2-<(trimethylsilyl)methyl>-2,6-octadienyl methanesulfonate

Guidance literature:: With triethylamine; In dichloromethane; at 0 ℃; for 1h;
DOI:10.1021/jo00043a014

Reference yield:

: 110481-61-3
3-trimethylsilyl-2-diethylphosphonopropionic acid ethyl ester

: 142720-34-1
(2E,6E)-8-(benzyloxy)-6-methyl-2-<(trimethylsilyl)methyl>-2,6-octadienyl methanesulfonate

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) KH, 2.) 18-crown-6 / 1.) THF, 0 deg C, 1.5 h, 2.) THF, -78 deg C, 6 h

2: 91 percent / AlCl₃, LiAlH₄ / diethyl ether / 5 h / 0 °C

3: 98 percent / triethylamine / CH₂Cl₂ / 1 h / 0 °C

With lithium aluminium tetrahydride; aluminium trichloride; 18-crown-6 ether; potassium hydride; triethylamine; In diethyl ether; dichloromethane;
DOI:10.1021/jo00043a014

Reference yield:

: 142720-30-7
ethyl (2E,6E)-8-(benzyloxy)-6-methyl-2-<(trimethylsilyl)methyl>-2,6-octadienoate

: 142720-34-1
(2E,6E)-8-(benzyloxy)-6-methyl-2-<(trimethylsilyl)methyl>-2,6-octadienyl methanesulfonate

Guidance literature:: Multi-step reaction with 2 steps

1: 91 percent / AlCl₃, LiAlH₄ / diethyl ether / 5 h / 0 °C

2: 98 percent / triethylamine / CH₂Cl₂ / 1 h / 0 °C

With lithium aluminium tetrahydride; aluminium trichloride; triethylamine; In diethyl ether; dichloromethane;
DOI:10.1021/jo00043a014