C₃₆H₃₆Si

Base Information

• Chemical Name: C₃₆H₃₆Si
• CAS No.: 1446026-22-7
• Molecular Formula: C₃₆H₃₆Si
• Molecular Weight: 496.767
• Mol file: 1446026-22-7.mol

Synonyms:C₃₆H₃₆Si

Chemical Property of C₃₆H₃₆Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of C₃₆H₃₆Si

There total 5 articles about C₃₆H₃₆Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.7%

bromobenzene (108-86-1,52753-63-6) + Si(C6H3-2,6-Mes2)HCl2 (220493-86-7) → C36H36Si (1446026-22-7)

Guidance literature:

bromobenzene; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 1h; Schlenk technique;

Si(C₆H₃-2,6-Mes₂)HCl₂; In tetrahydrofuran; at -78 - 20 ℃; Schlenk technique;

DOI:10.1021/ja400306h

Reference yield:

1,3-Dichlorobenzene (541-73-1) → C36H36Si (1446026-22-7)

Guidance literature:

Multi-step reaction with 3 steps

1.1: n-butyllithium / tetrahydrofuran / 1.5 h / -80 °C / Inert atmosphere

1.2: 20 °C / Inert atmosphere; Reflux

1.3: 0 °C

2.1: n-butyllithium / hexane / 16 h / Inert atmosphere

2.2: -85 - 20 °C / Inert atmosphere

3.1: n-butyllithium / tetrahydrofuran / 1 h / -78 °C / Schlenk technique

3.2: -78 - 20 °C / Schlenk technique

With n-butyllithium; In tetrahydrofuran; hexane;

DOI:10.1021/ja400306h

Reference yield:

2,6-dimesityliodobenzene (153414-10-9) → C36H36Si (1446026-22-7)

Guidance literature:

Multi-step reaction with 2 steps

1.1: n-butyllithium / hexane / 16 h / Inert atmosphere

1.2: -85 - 20 °C / Inert atmosphere

2.1: n-butyllithium / tetrahydrofuran / 1 h / -78 °C / Schlenk technique

2.2: -78 - 20 °C / Schlenk technique

With n-butyllithium; In tetrahydrofuran; hexane;

DOI:10.1021/ja400306h

upstream raw materials:

benzene-d6

tri-n-butyl-tin hydride

2,6-dimesityliodobenzene

1,3-Dichlorobenzene