(3aS,3bR,9bR,10R,11S,11aR)-11-hydroxy-2,2-dimethyl-4-(4-methylphenylsulfonyl)-10-phenylcarbonyloxy-7,8-di(trimethylsilyl)-3a,3b,4,5,9b,10,11,11a-octahydro[1,3]dioxolo[4,5-c]phenanthridine

Base Information

Chemical Name:(3aS,3bR,9bR,10R,11S,11aR)-11-hydroxy-2,2-dimethyl-4-(4-methylphenylsulfonyl)-10-phenylcarbonyloxy-7,8-di(trimethylsilyl)-3a,3b,4,5,9b,10,11,11a-octahydro[1,3]dioxolo[4,5-c]phenanthridine
CAS No.:872221-85-7
Molecular Formula:C₃₆H₄₇NO₇SSi₂
Molecular Weight:694.009
Hs Code.:

(3aS,3bR,9bR,10R,11S,11aR)-11-hydroxy-2,2-dimethyl-4-(4-methylphenylsulfonyl)-10-phenylcarbonyloxy-7,8-di(trimethylsilyl)-3a,3b,4,5,9b,10,11,11a-octahydro[1,3]dioxolo[4,5-c]phenanthridine

Synonyms:(3aS,3bR,9bR,10R,11S,11aR)-11-hydroxy-2,2-dimethyl-4-(4-methylphenylsulfonyl)-10-phenylcarbonyloxy-7,8-di(trimethylsilyl)-3a,3b,4,5,9b,10,11,11a-octahydro[1,3]dioxolo[4,5-c]phenanthridine

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Chemical Property of (3aS,3bR,9bR,10R,11S,11aR)-11-hydroxy-2,2-dimethyl-4-(4-methylphenylsulfonyl)-10-phenylcarbonyloxy-7,8-di(trimethylsilyl)-3a,3b,4,5,9b,10,11,11a-octahydro[1,3]dioxolo[4,5-c]phenanthridine

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Technology Process of (3aS,3bR,9bR,10R,11S,11aR)-11-hydroxy-2,2-dimethyl-4-(4-methylphenylsulfonyl)-10-phenylcarbonyloxy-7,8-di(trimethylsilyl)-3a,3b,4,5,9b,10,11,11a-octahydro[1,3]dioxolo[4,5-c]phenanthridine

There total 1 articles about (3aS,3bR,9bR,10R,11S,11aR)-11-hydroxy-2,2-dimethyl-4-(4-methylphenylsulfonyl)-10-phenylcarbonyloxy-7,8-di(trimethylsilyl)-3a,3b,4,5,9b,10,11,11a-octahydro[1,3]dioxolo[4,5-c]phenanthridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 872221-80-2
(3aS,3bR,9bR,10R,11S,11aS)-2,2-dimethyl-4-(4-methylphenylsulfonyl)-10-phenylcarbonyloxy-11-(tert-butyldimethylsilyloxy)-7,8-di(trimethylsilyl)-3a,3b,4,5,9b,10,11,11a-octahydro[1,3]dioxolo[4,5-c]phenanthridine

: 872221-85-7
(3aS,3bR,9bR,10R,11S,11aR)-11-hydroxy-2,2-dimethyl-4-(4-methylphenylsulfonyl)-10-phenylcarbonyloxy-7,8-di(trimethylsilyl)-3a,3b,4,5,9b,10,11,11a-octahydro[1,3]dioxolo[4,5-c]phenanthridine

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 20 ℃;
DOI:10.1139/V06-078

Reference yield:

: 872221-85-7
(3aS,3bR,9bR,10R,11S,11aR)-11-hydroxy-2,2-dimethyl-4-(4-methylphenylsulfonyl)-10-phenylcarbonyloxy-7,8-di(trimethylsilyl)-3a,3b,4,5,9b,10,11,11a-octahydro[1,3]dioxolo[4,5-c]phenanthridine

: 872221-87-9
(3aS,3bR,9bR,10R,11S,11aS)-2,2-dimethyl-4-(4-methylphenylsulfonyl)-5-oxo-10,11-di(phenylcarbonyloxy)-7,8-di(trimethylsilyl)-3a,3b,4,5,9b,10,11,11a-octahydro[1,3]dioxolo[4,5-c]phenanthridine

Guidance literature:: Multi-step reaction with 2 steps

1: 86 percent / pyridine / 4 h / 20 °C

2: 33 percent / NaIO₄; RuCl₃*H₂O; Na₂CO₃ / acetonitrile; CCl₄; H₂O / 20 °C

With pyridine; ruthenium trichloride; sodium periodate; sodium carbonate; In tetrachloromethane; water; acetonitrile;
DOI:10.1139/V06-078

Reference yield:

: 872221-85-7
(3aS,3bR,9bR,10R,11S,11aR)-11-hydroxy-2,2-dimethyl-4-(4-methylphenylsulfonyl)-10-phenylcarbonyloxy-7,8-di(trimethylsilyl)-3a,3b,4,5,9b,10,11,11a-octahydro[1,3]dioxolo[4,5-c]phenanthridine

: C₃₆H₄₃NO₇Si₂

Guidance literature:: Multi-step reaction with 3 steps

1: 86 percent / pyridine / 4 h / 20 °C

2: 33 percent / NaIO₄; RuCl₃*H₂O; Na₂CO₃ / acetonitrile; CCl₄; H₂O / 20 °C

3: sodium naphthalide / tetrahydrofuran / -65 °C

With pyridine; ruthenium trichloride; sodium periodate; sodium naphthalenide; sodium carbonate; In tetrahydrofuran; tetrachloromethane; water; acetonitrile;
DOI:10.1139/V06-078