tris(2-chloro phenyl)boroxine

Base Information

• Chemical Name: tris(2-chloro phenyl)boroxine
• CAS No.: 79422-00-7
• Molecular Formula: C₁₈H₁₂B₃Cl₃O₃
• Molecular Weight: 415.083
• Mol file: 79422-00-7.mol

Synonyms:tris(2-chloro phenyl)boroxine

Chemical Property of tris(2-chloro phenyl)boroxine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tris(2-chloro phenyl)boroxine

There total 6 articles about tris(2-chloro phenyl)boroxine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-Chlorobenzeneboronic acid (3900-89-8) → tris(2-chloro phenyl)boroxine (79422-00-7)

Guidance literature:

With sulfuric acid;

DOI:10.1021/ja01319a053

Reference yield:

2-chlorophenylmagnesium bromide (36692-27-0) + boric acid tributyl ester (688-74-4) → tris(2-chloro phenyl)boroxine (79422-00-7)

Guidance literature:

In diethyl ether; byproducts: H2O; synthesis of dihydroxy borane at -75°C in ether, dehydration by heating in vac. to 80°C (12h), then to 110°C (4h);;

DOI:10.1021/ja01350a045

Reference yield:

2-chlorophenylmagnesium bromide (36692-27-0) → tris(2-chloro phenyl)boroxine (79422-00-7)

Guidance literature:

Multi-step reaction with 2 steps

1: diethyl ether / und anschliessenden Hydrolyse

2: beim Erhitzen

With diethyl ether;

DOI:10.1021/ja01319a053

upstream raw materials:

2-Chlorobenzeneboronic acid

2-chlorophenylmagnesium bromide

boric acid tributyl ester

triisobutyl borate

Downstream raw materials:

2-(2-chlorophenyl)malonic acid diethyl ester

3-(2-chlorophenyl)fluoranthene

2,7-di-tert-butyl-4,10-bis(2-chlorophenyl)pyrene

2,7-di-tert-butyl-4,10-bis(2-chlorophenyl)pyrene