3-Benzoyl-benzoic acid (2E,6E)-8-(tert-butyl-dimethyl-silanyloxy)-2,6-dimethyl-octa-2,6-dienyl ester

Base Information

Chemical Name:3-Benzoyl-benzoic acid (2E,6E)-8-(tert-butyl-dimethyl-silanyloxy)-2,6-dimethyl-octa-2,6-dienyl ester
CAS No.:618405-46-2
Molecular Formula:C₃₀H₄₀O₄Si
Molecular Weight:492.731
Hs Code.:

Synonyms:3-Benzoyl-benzoic acid (2E,6E)-8-(tert-butyl-dimethyl-silanyloxy)-2,6-dimethyl-octa-2,6-dienyl ester

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Chemical Property of 3-Benzoyl-benzoic acid (2E,6E)-8-(tert-butyl-dimethyl-silanyloxy)-2,6-dimethyl-octa-2,6-dienyl ester

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Technology Process of 3-Benzoyl-benzoic acid (2E,6E)-8-(tert-butyl-dimethyl-silanyloxy)-2,6-dimethyl-octa-2,6-dienyl ester

There total 3 articles about 3-Benzoyl-benzoic acid (2E,6E)-8-(tert-butyl-dimethyl-silanyloxy)-2,6-dimethyl-octa-2,6-dienyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 579-18-0
3-benzoylbenzoic acid

: 127586-84-9
8-<<(1,1-dimethylethyl)dimethylsilyl>oxy>-2,6-dimethyl-2(E),6(E)-octadien-1-ol

: 618405-46-2
3-Benzoyl-benzoic acid (2E,6E)-8-(tert-butyl-dimethyl-silanyloxy)-2,6-dimethyl-octa-2,6-dienyl ester

Guidance literature:: With dmap; diisopropyl-carbodiimide; In dichloromethane; at 20 ℃;
DOI:10.1021/ja036178d

Reference yield:

: 80873-81-0
geraniol tert-butyldimethylsilyl ether

: 618405-46-2
3-Benzoyl-benzoic acid (2E,6E)-8-(tert-butyl-dimethyl-silanyloxy)-2,6-dimethyl-octa-2,6-dienyl ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: SeO₂; t-BuOOH; salycylic acid / CH₂Cl₂; H₂O; various solvent(s) / 12 h

1.2: 50 percent / NaBH₄ / methanol

2.1: 69 percent / DMAP; diisopropylcarbodiimide / CH₂Cl₂ / 20 °C

With tert.-butylhydroperoxide; dmap; selenium(IV) oxide; salicylic acid; diisopropyl-carbodiimide; In dichloromethane; water; 2.1: Steglich reaction;
DOI:10.1021/ja036178d

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 618405-46-2
3-Benzoyl-benzoic acid (2E,6E)-8-(tert-butyl-dimethyl-silanyloxy)-2,6-dimethyl-octa-2,6-dienyl ester

Guidance literature:: Multi-step reaction with 3 steps

1.1: 100 percent / i-Pr₂NEt / CH₂Cl₂ / 20 °C

2.1: SeO₂; t-BuOOH; salycylic acid / CH₂Cl₂; H₂O; various solvent(s) / 12 h

2.2: 50 percent / NaBH₄ / methanol

3.1: 69 percent / DMAP; diisopropylcarbodiimide / CH₂Cl₂ / 20 °C

With tert.-butylhydroperoxide; dmap; selenium(IV) oxide; N-ethyl-N,N-diisopropylamine; salicylic acid; diisopropyl-carbodiimide; In dichloromethane; water; 3.1: Steglich reaction;
DOI:10.1021/ja036178d