Technology Process of acetoxy(acetoxymethyl)diphenylgermane
There total 1 articles about acetoxy(acetoxymethyl)diphenylgermane which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
acetic acid; triethylamine;
In
acetic acid; toluene;
(N2); dropwise addn. of glacial acetic acid to the mixt. with stirring and ice cooling; then stirring (8 h) under reflux;; filtration; washing (petrolether); removal of solvent and excess triethyl amine; addn. of petrolether to the residue; decanting the petroleum ether phase; then distg. the solvent off; vacuum distn.; recrystn. (diethylether/petroleum ether); elem. anal.;
DOI:10.1016/0022-328X(88)87040-2
- Guidance literature:
-
With
hydrogenchloride; sodium hydrogencarbonate; sodium sulfate;
In
diethyl ether;
(N2); dropwise addn. ( 30 min) of acetoxy(acetoxymethyl)diphenylgermane into the suspn. of Li(AlH4) under stirring and ice cooling; then stirring (6 h) under reflux and addnl. 15 h at room temp.; diln. with petroleum ether; addn. of aq. HCl at 0 °C; extn.(petroleum ether); washing (NaHCO3); drying over Na2SO4; then distg. the solvent off; vacuum distn.; elem. anal.;
DOI:10.1016/0022-328X(88)87040-2
