Germane, chloro(chloromethyl)diphenyl-

Base Information

Chemical Name:Germane, chloro(chloromethyl)diphenyl-
CAS No.:98068-28-1
Molecular Formula:C13H12Cl2Ge
Molecular Weight:311.734
Hs Code.:

Synonyms:

Suppliers and Price of Germane, chloro(chloromethyl)diphenyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Germane, chloro(chloromethyl)diphenyl-

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Germane, chloro(chloromethyl)diphenyl-

There total 2 articles about Germane, chloro(chloromethyl)diphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 100-59-4
phenylmagnesium chloride

: 21572-18-9
trichloro(chloromethyl)germane

: 98068-28-1
chloro(chloromethyl)diphenylgermane

Guidance literature:: In tetrahydrofuran; diethyl ether; (N2); dropwise addn. of a soln. of phenyl magnesium chloride into the soln. of GeCl3CH2Cl under water cooling; stirring (3 h) at room temp. then 1.5 h under reflux;; filtration; washing (petrolether); solvent evapn.; vacuum distn.;
DOI:10.1016/0022-328X(88)87040-2

Reference yield: 56.0%

: 100-59-4
phenylmagnesium chloride

: 21572-18-9
trichloro(chloromethyl)germane

: 98068-28-1
chloro(chloromethyl)diphenylgermane

: 19089-97-5
dichloro(chloromethyl)phenylgermane

Guidance literature:: In tetrahydrofuran; diethyl ether; to a soln. of Ge-compd. in diethyl ether is added a soln. of phenylmagnesium chloride in THF at -70°C during 2 h, mixt. is allowed to warm to room temp. and then stirred under reflux for 3 h (N2); ppt. is filtd. off, washed with petroleum ether, filtrate is evapd. to dryness, residue is distd. in vac. (Vigreux column);

Reference yield: 84.0%

: 98068-28-1
chloro(chloromethyl)diphenylgermane

: 3536-96-7
vinylmagnesium chloride

: 182305-43-7
(chlormethyl)diphenyl(vinyl)germane

Guidance literature:: In tetrahydrofuran; toluene; N2-atmosphere; dropwise addn. of Grignard reagent (in THF) to germane (in PhMe; over 30 min, room temp., stirring), refluxing for 1 h; cooling to room temp., addn. of aq. NH4Cl (0°C), extn. of aq. layer (Et2O), drying org. layers (MgSO4), solvent removal (reduced pressure), fractional distn. (vac.), chromy. (SiO2, hexane), distn. (140°C/0.01 Torr); elem. anal.;
DOI:10.1016/0022-328X(96)06300-0