phenyl 2-O-(4-methoxybenzoyl)-3,4-di-O-triethylsilyl-β-D-xylopyranosyl-(1->3)-2-O-acetyl-1-thio-α-L-arabinopyranoside

Base Information

Chemical Name:phenyl 2-O-(4-methoxybenzoyl)-3,4-di-O-triethylsilyl-β-D-xylopyranosyl-(1->3)-2-O-acetyl-1-thio-α-L-arabinopyranoside
CAS No.:321125-12-6
Molecular Formula:C₃₈H₅₈O₁₁SSi₂
Molecular Weight:779.109
Hs Code.:

Synonyms:phenyl 2-O-(4-methoxybenzoyl)-3,4-di-O-triethylsilyl-β-D-xylopyranosyl-(1->3)-2-O-acetyl-1-thio-α-L-arabinopyranoside

Suppliers and Price of phenyl 2-O-(4-methoxybenzoyl)-3,4-di-O-triethylsilyl-β-D-xylopyranosyl-(1->3)-2-O-acetyl-1-thio-α-L-arabinopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of phenyl 2-O-(4-methoxybenzoyl)-3,4-di-O-triethylsilyl-β-D-xylopyranosyl-(1->3)-2-O-acetyl-1-thio-α-L-arabinopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of phenyl 2-O-(4-methoxybenzoyl)-3,4-di-O-triethylsilyl-β-D-xylopyranosyl-(1->3)-2-O-acetyl-1-thio-α-L-arabinopyranoside

There total 3 articles about phenyl 2-O-(4-methoxybenzoyl)-3,4-di-O-triethylsilyl-β-D-xylopyranosyl-(1->3)-2-O-acetyl-1-thio-α-L-arabinopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 321125-07-9
2-O-(4-methoxybenzoyl)-3,4-di-O-triethylsilyl-α,β-D-xylopyranosyl trichloroacetimidate

: 321125-10-4
phenyl 2-O-acetyl-1-thio-1-deoxy-α-L-arabinopyranoside

: 321125-12-6
phenyl 2-O-(4-methoxybenzoyl)-3,4-di-O-triethylsilyl-β-D-xylopyranosyl-(1->3)-2-O-acetyl-1-thio-α-L-arabinopyranoside

: 321125-11-5
phenyl 2-O-(4-methoxybenzoyl)-3,4-di-O-triethylsilyl-β-D-xylopyranosyl-(1->4)-2-O-acetyl-1-thio-α-L-arabinopyranoside

Guidance literature:: 2-O-(4-methoxybenzoyl)-3,4-di-O-triethylsilyl-α,β-D-xylopyranosyl trichloroacetimidate; phenyl 2-O-acetyl-1-thio-1-deoxy-α-L-arabinopyranoside; With 4 Angstroem MS; In dichloromethane; at 20 ℃; for 0.333333h;

With boron trifluoride diethyl etherate; In dichloromethane; at -78 ℃; for 0.666667h;
DOI:10.1016/S0008-6215(00)00225-1

Reference yield:

: 153984-54-4
phenyl 3,4-O-isopropylidene-1-thio-α-L-arabinopyranoside

: 321125-12-6
phenyl 2-O-(4-methoxybenzoyl)-3,4-di-O-triethylsilyl-β-D-xylopyranosyl-(1->3)-2-O-acetyl-1-thio-α-L-arabinopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1.1: 74 percent / pyridine / 20 °C

2.1: 98 percent / acetic acid; H₂O / 1 h / 70 °C

3.1: 4 Angstroem MS / CH₂Cl₂ / 0.33 h / 20 °C

3.2: 20 percent / BF₃*OEt₂ / CH₂Cl₂ / 0.67 h / -78 °C

With 4 Angstroem MS; In pyridine; dichloromethane; water; acetic acid;
DOI:10.1016/S0008-6215(00)00225-1

Reference yield:

: 321125-09-1
phenyl 2-O-acetyl-3,4-O-isopropylidene-1-thio-α-L-arabinopyranoside

: 321125-12-6
phenyl 2-O-(4-methoxybenzoyl)-3,4-di-O-triethylsilyl-β-D-xylopyranosyl-(1->3)-2-O-acetyl-1-thio-α-L-arabinopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1.1: 98 percent / acetic acid; H₂O / 1 h / 70 °C

2.1: 4 Angstroem MS / CH₂Cl₂ / 0.33 h / 20 °C

2.2: 20 percent / BF₃*OEt₂ / CH₂Cl₂ / 0.67 h / -78 °C

With 4 Angstroem MS; In dichloromethane; water; acetic acid;
DOI:10.1016/S0008-6215(00)00225-1