methyl 2,12-bis(9-anthracenyl)-7-phenyl-5,6,8,9-tetrahydro-1,13-diazadibenzanthracene-14-carboxylate

Base Information

• Chemical Name: methyl 2,12-bis(9-anthracenyl)-7-phenyl-5,6,8,9-tetrahydro-1,13-diazadibenzanthracene-14-carboxylate
• CAS No.: 129363-22-0
• Molecular Formula: C₅₆H₃₈N₂O₂
• Molecular Weight: 770.93
• Mol file: 129363-22-0.mol

Synonyms:methyl 2,12-bis(9-anthracenyl)-7-phenyl-5,6,8,9-tetrahydro-1,13-diazadibenzanthracene-14-carboxylate

Chemical Property of methyl 2,12-bis(9-anthracenyl)-7-phenyl-5,6,8,9-tetrahydro-1,13-diazadibenzanthracene-14-carboxylate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl 2,12-bis(9-anthracenyl)-7-phenyl-5,6,8,9-tetrahydro-1,13-diazadibenzanthracene-14-carboxylate

There total 5 articles about methyl 2,12-bis(9-anthracenyl)-7-phenyl-5,6,8,9-tetrahydro-1,13-diazadibenzanthracene-14-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

9-phenanthrenylmagnesium bromide (92103-92-9) + methyl 2,12-7-phenyl-5,6,7,8-tetrahydro-1,13-diazadibenzanthracene-14-carboxylate (130883-20-4) → methyl 2,12-bis(9-anthracenyl)-7-phenyl-5,6,8,9-tetrahydro-1,13-diazadibenzanthracene-14-carboxylate (129363-22-0)

Guidance literature:

DOI:10.1021/jo00303a006

Reference yield:

2,12-Dibromo-7-phenyl-5,7,8,9-tetrahydro-6H-14-oxa-1,13-diaza-dibenzo[a,j]anthracene (130883-19-1) → methyl 2,12-bis(9-anthracenyl)-7-phenyl-5,6,8,9-tetrahydro-1,13-diazadibenzanthracene-14-carboxylate (129363-22-0)

Guidance literature:

Multi-step reaction with 2 steps

2: 1.) magnesium, 1,2-dibromoethane, iodine, 2.) Ni(acac)2 / 1.) Et₂O, 50 deg C, 1 h, 2.) a) benzene, 0 deg C, 1 h, b) reflux, 24 h

With bis(acetylacetonate)nickel(II); iodine; magnesium; ethylene dibromide;

DOI:10.1021/ja00001a027

Reference yield:

9-Bromoanthracene (1564-64-3) + methyl 2,12-7-phenyl-5,6,7,8-tetrahydro-1,13-diazadibenzanthracene-14-carboxylate (130883-20-4) → methyl 2,12-bis(9-anthracenyl)-7-phenyl-5,6,8,9-tetrahydro-1,13-diazadibenzanthracene-14-carboxylate (129363-22-0)

Guidance literature:

With bis(acetylacetonate)nickel(II); iodine; magnesium; ethylene dibromide; Yield given. Multistep reaction; 1.) Et₂O, 50 deg C, 1 h, 2.) a) benzene, 0 deg C, 1 h, b) reflux, 24 h;

DOI:10.1021/ja00001a027

upstream raw materials:

9-Bromoanthracene

methyl 2,12-7-phenyl-5,6,7,8-tetrahydro-1,13-diazadibenzanthracene-14-carboxylate

9-phenanthrenylmagnesium bromide

methyl 2,12-dichloro-7-phenyl-5,6,7,8-tetrahydro-1,13-diazadibenzanthracene-14-carboxylate

Downstream raw materials:

2,12-bis(9-anthracenyl)-7-phenyl-5,6,8,9-tetrahydro-1,13-diazadibenzanthracene-14-carboxylic acid