TlS(2,4,6-iPr₃-Ph)

Base Information

Chemical Name:TlS(2,4,6-iPr₃-Ph)
CAS No.:871941-09-2
Molecular Formula:C₁₅H₂₃S*Tl
Molecular Weight:439.797
Hs Code.:

Synonyms:TlS(2,4,6-iPr₃-Ph)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of TlS(2,4,6-iPr₃-Ph)

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Technology Process of TlS(2,4,6-iPr₃-Ph)

There total 1 articles about TlS(2,4,6-iPr₃-Ph) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 22693-41-0
2,4,6-Triisopropylthiophenol

: 20398-06-5
thallium (I) ethoxide

: 871941-09-2
TlS(2,4,6-iPr₃-Ph)

Guidance literature:: In petroleum ether; Schlenk or glovebox techniquie, under N2; thiol (0.2 g) dissolved in petroleum ether (10 ml) and minimal amt. of THF (if necessary); soln. of thallium ethoxide (one equiv.) in petroleum ether (4 ml) added; stirred indark; ppt. collected; washed with petroleum ether; dried;
DOI:10.1021/ja045310m

Reference yield: 68.0%

: 388110-50-7
[PhBP₃]CoI

: 871941-09-2
TlS(2,4,6-iPr₃-Ph)

: [PhBP₃]CoS(2,4,6-iPr₃-Ph)

Guidance literature:: In tetrahydrofuran; byproducts: TlI; Schlenk or glavebox technique, under N2; THF (4 ml) soln. of TlS(2,4,6-iPr3-Ph) (0.265 mmol) added dropwise to stirring soln. of Co complex (0.265 mmol) in THF (8 ml); stirred (10 h); TlI filtered off; THF removed (vac.); solid dissolved in benzene (4 ml);vapor diffusion of petroleum ether; crystals dried; recrystd. from benz ene/petroleum ether; elem. anal.;
DOI:10.1021/ja045310m