22693-41-0

Basic information

• Product Name: Benzenethiol, 2,4,6-tris(1-methylethyl)-
• CAS NO: 22693-41-0
• Molecular Formula: C15H24S
• Molecular Weight: 236.422
• Mol File: 22693-41-0.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: Benzenethiol, 2,4,6-tris(1-methylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenethiol, 2,4,6-tris(1-methylethyl)-(22693-41-0)
• EPA Substance Registry System: Benzenethiol, 2,4,6-tris(1-methylethyl)-(22693-41-0)

Safety Data

• Hazardous Substances Data: 22693-41-0(Hazardous Substances Data)

Upstream product

• 6553-96-4 2,4,6-triisopropylphenylsulfonyl chloride 
• 78089-44-8 n-Butyl 2,4,6-triisopropylphenyl sulfide 
• 78089-47-1 n-Butyl 2,4,6-triisopropylphenyl sulfoxide 
• 108-98-5 thiophenol 
• 989-39-9 S-(2,4,6-triisopropylphenyl) 2,4,6-triisopropylbenzenesulfinothioate 
• 20875-34-7 1,2-bis(2,4,6-triisopropylphenyl)disulfane 

Downstream Products

• 22693-43-2 1-<2.4.6-Tri-isopropyl-phenylmercapto>-1.3.5-tri-tert.-butyl-cyclohexadien-(2.5)-on-(4) 
• 160788-43-2 S-Deuteriated 2,4,6-triisopropylbenzenethiol 
• 342885-84-1 methyl 3-[(2,4,6-triisopropylphenyl)sulfenyl]propionate 
• 989-39-9 S-(2,4,6-triisopropylphenyl) 2,4,6-triisopropylbenzenesulfinothioate 
• 1062-30-2 (2,4,6-Triisopropyl-phenyl)-2,4,6-triisopropyl-benzothiolsulfonat 
• 78089-43-7 tert-Butyl 2,4,6-triisopropylphenyl sulfide 
• 78089-47-1 n-Butyl 2,4,6-triisopropylphenyl sulfoxide 
• 78089-46-0 tert-Butyl 2,4,6-triisopropylphenyl sulfoxide 
• 78089-49-3 Methyl trans-<(2,4,6-triisopropylphenyl)sulfinyl>acrylate 
• 113584-54-6 ⁽⁹⁹⁾Tc(2,4,6-triisopropylbenzenethiolate)3(CH₃CN)2 
• 111557-28-9 W(S)(O-2,6-C₆H₃Me₂)4 
• 111975-83-8 {tungsten(C-t-Bu)(2,4,6-triisopropylbenzenethiolate)3Cl}{HNEt₃} 
• 554-68-7 triethylamine hydrochloride 
• 112043-96-6 Zn(SC₆H₂(C₃H₇)3)2(C₅H₄N)2 

Relevant articles and documents

Mechanistic Investigation and Optimization of Photoredox Anti-Markovnikov Hydroamination

The reaction mechanism and the origin of the selectivity for the photocatalytic intermolecular anti-Markovnikov hydroamination of unactivated alkenes with primary amines to furnish secondary amines have been revealed by time-resolved laser kinetics measur

Intermolecular Anti-Markovnikov Hydroamination of Unactivated Alkenes with Sulfonamides Enabled by Proton-Coupled Electron Transfer

Here we report a catalytic method for the intermolecular anti-Markovnikov hydroamination of unactivated alkenes using primary and secondary sulfonamides. These reactions occur at room temperature under visible light irradiation and are jointly catalyzed by an iridium(III) photocatalyst, a dialkyl phosphate base, and a thiol hydrogen atom donor. Reaction outcomes are consistent with the intermediacy of an N-centered sulfonamidyl radical generated via proton-coupled electron transfer activation of the sulfonamide N-H bond. Studies outlining the synthetic scope (>60 examples) and mechanistic features of the reaction are presented.

A convergent asymmetric synthesis of γ-butenolides

The addition of aldehydes to the new enantiomerically pure lithiated sulfoxide-orthoester 13 yielded γ-butenolides of high enantiomeric purities after elimination of phenylsulfinic acid. The cyclocondensation with ketones was less stereoselective. This new asymmetric synthesis of γ-butenolides has been applied to a convergent preparation of the antifungal antibiotic (+)-cerulenin.