N-p-toluenesulfonyl-1-trioxa-4,10,16-triaza-1,7,13-cyclooctadecanedione-6,14

Base Information

• Chemical Name: N-p-toluenesulfonyl-1-trioxa-4,10,16-triaza-1,7,13-cyclooctadecanedione-6,14
• CAS No.: 78631-00-2
• Molecular Formula: C₁₉H₂₉N₃O₇S
• Molecular Weight: 443.521
• Mol file: 78631-00-2.mol

Synonyms:N-p-toluenesulfonyl-1-trioxa-4,10,16-triaza-1,7,13-cyclooctadecanedione-6,14

Chemical Property of N-p-toluenesulfonyl-1-trioxa-4,10,16-triaza-1,7,13-cyclooctadecanedione-6,14

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-p-toluenesulfonyl-1-trioxa-4,10,16-triaza-1,7,13-cyclooctadecanedione-6,14

There total 6 articles about N-p-toluenesulfonyl-1-trioxa-4,10,16-triaza-1,7,13-cyclooctadecanedione-6,14 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

2,2'-diaminodiethyl ether (2752-17-2) + dichloure de N-p-toluenesulfonyl dioxa-3,9-aza-6-undecanedioyle-1,11 (78630-99-6) → N-p-toluenesulfonyl-1-trioxa-4,10,16-triaza-1,7,13-cyclooctadecanedione-6,14 (78631-00-2)

Guidance literature:

In benzene; for 8h;

DOI:10.1002/hlca.19810640410

Reference yield:

N-tosyldiethanolamine (7146-67-0) → N-p-toluenesulfonyl-1-trioxa-4,10,16-triaza-1,7,13-cyclooctadecanedione-6,14 (78631-00-2)

Guidance literature:

Multi-step reaction with 3 steps

1: 75 percent / NaH / tetrahydrofuran / 24 h / 25 °C

2: ClCOCOCl, pyridine / benzene

3: benzene

With pyridine; oxalyl dichloride; sodium hydride; In tetrahydrofuran; benzene;

DOI:10.1039/c39890000608

Reference yield:

N-p-toluenesulfonyldioxa-3,9-aza-6-undecanedioique-1,11 (78630-98-5) → N-p-toluenesulfonyl-1-trioxa-4,10,16-triaza-1,7,13-cyclooctadecanedione-6,14 (78631-00-2)

Guidance literature:

Multi-step reaction with 2 steps

1: ClCOCOCl, pyridine / benzene

2: benzene

With pyridine; oxalyl dichloride; In benzene;

DOI:10.1039/c39890000608

upstream raw materials:

2,2'-diaminodiethyl ether

dichloure de N-p-toluenesulfonyl dioxa-3,9-aza-6-undecanedioyle-1,11

N-tosyldiethanolamine

N-p-toluenesulfonyldioxa-3,9-aza-6-undecanedioique-1,11

Downstream raw materials:

di-p-toluenesulfonyl-7,9-pentaoxa-4,10,16,22,27-tetraaza-1,7,13,19-bicyclo<11.11.5>nonacosanedione-2,12

1-<(4-methylphenyl)sylfonyl>-7,13-dimethyl-1,7,13-triaza-4,10,16-trioxacyclooctadecane-6,14-dione

4,10-Dimethyl-16-(toluene-4-sulfonyl)-1,7,13-trioxa-4,10,16-triaza-cyclooctadecane

N-p-toluenesulfonyl-1-trioxa-4,10,16-triaza-1,7,13-cyclooctadecane