(1'S,2S,2'R,3S)-S-[2'-(N-benzyl-N-mesitylenesulfonylamino)-1'-phenylpropyl] 2-(tert-butyl(diphenyl)silyloxy)-3-hydroxy-3-piperonylthiopropionate

Base Information

Chemical Name:(1'S,2S,2'R,3S)-S-[2'-(N-benzyl-N-mesitylenesulfonylamino)-1'-phenylpropyl] 2-(tert-butyl(diphenyl)silyloxy)-3-hydroxy-3-piperonylthiopropionate
CAS No.:1088697-49-7
Molecular Formula:C₅₁H₅₅NO₇S₂Si
Molecular Weight:886.218
Hs Code.:

Synonyms:(1'S,2S,2'R,3S)-S-[2'-(N-benzyl-N-mesitylenesulfonylamino)-1'-phenylpropyl] 2-(tert-butyl(diphenyl)silyloxy)-3-hydroxy-3-piperonylthiopropionate

Suppliers and Price of (1'S,2S,2'R,3S)-S-[2'-(N-benzyl-N-mesitylenesulfonylamino)-1'-phenylpropyl] 2-(tert-butyl(diphenyl)silyloxy)-3-hydroxy-3-piperonylthiopropionate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (1'S,2S,2'R,3S)-S-[2'-(N-benzyl-N-mesitylenesulfonylamino)-1'-phenylpropyl] 2-(tert-butyl(diphenyl)silyloxy)-3-hydroxy-3-piperonylthiopropionate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (1'S,2S,2'R,3S)-S-[2'-(N-benzyl-N-mesitylenesulfonylamino)-1'-phenylpropyl] 2-(tert-butyl(diphenyl)silyloxy)-3-hydroxy-3-piperonylthiopropionate

There total 1 articles about (1'S,2S,2'R,3S)-S-[2'-(N-benzyl-N-mesitylenesulfonylamino)-1'-phenylpropyl] 2-(tert-butyl(diphenyl)silyloxy)-3-hydroxy-3-piperonylthiopropionate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 120-57-0,30024-74-9
piperonal

: 1088697-38-4
(1'S,2'R)-S-[2'-(N-benzyl-N-mesitylenesulfonylamino)-1'-phenylpropyl] 2-(tert-butyl(diphenyl)silyloxy)-thioacetate

: 1088697-49-7
(1'S,2S,2'R,3S)-S-[2'-(N-benzyl-N-mesitylenesulfonylamino)-1'-phenylpropyl] 2-(tert-butyl(diphenyl)silyloxy)-3-hydroxy-3-piperonylthiopropionate

: 1088697-70-4
(1'S,2R,2'R,3R)-S-[2'-(N-benzyl-N-mesitylenesulfonylamino)-1'-phenylpropyl] 2-(tert-butyl(diphenyl)silyloxy)-3-hydroxy-3-piperonylthiopropionate

Guidance literature:: (1'S,2'R)-S-[2'-(N-benzyl-N-mesitylenesulfonylamino)-1'-phenylpropyl] 2-(tert-butyl(diphenyl)silyloxy)-thioacetate; With triethylamine; dicyclohexyl(((trifluoromethyl)sulfonyl)oxy)borane; In hexane; dichloromethane; at -78 ℃; for 1h; Inert atmosphere;

piperonal; In hexane; dichloromethane; at -78 - 0 ℃; for 4h; optical yield given as %de; diastereoselective reaction; Inert atmosphere;
DOI:10.1021/jo801720v