Technology Process of ethyl naphthalen-2-yl(phenyl)phosphinate
There total 4 articles about ethyl naphthalen-2-yl(phenyl)phosphinate which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
phthalimide; nickel(II) bromide trihydrate; tetraethylammonium hexafluorophosphate; caesium carbonate; 4,4'-di-tert-butyl-2,2'-bipyridine;
In
N,N-dimethyl acetamide;
at 20 ℃;
for 3h;
Electrochemical reaction;
Schlenk technique;
Inert atmosphere;
DOI:10.1021/acs.orglett.9b02475
- Guidance literature:
-
With
bis(1,5-cyclooctadiene)nickel (0); potassium carbonate; 1,2-bis-(dicyclohexylphosphino)ethane;
In
1,4-dioxane;
at 100 ℃;
for 18h;
Inert atmosphere;
Schlenk technique;
DOI:10.1021/ja512498u
- Guidance literature:
-
Multi-step reaction with 2 steps
1: tetrahydrofuran / 20 h / 0 - 20 °C / Inert atmosphere; Schlenk technique
2: nickel(II) bromide trihydrate; phthalimide; 4,4'-di-tert-butyl-2,2'-bipyridine; caesium carbonate; tetraethylammonium hexafluorophosphate / N,N-dimethyl acetamide / 3 h / 20 °C / Electrochemical reaction; Schlenk technique; Inert atmosphere
With
phthalimide; nickel(II) bromide trihydrate; tetraethylammonium hexafluorophosphate; caesium carbonate; 4,4'-di-tert-butyl-2,2'-bipyridine;
In
tetrahydrofuran; N,N-dimethyl acetamide;
DOI:10.1021/acs.orglett.9b02475
