{(C₆H₅)2PCH₂CH₂}3NNiCO

Base Information

Chemical Name:{(C₆H₅)2PCH₂CH₂}3NNiCO
CAS No.:88440-32-8
Molecular Formula:C₄₃H₄₂NNiOP₃
Molecular Weight:740.424
Hs Code.:

{(C<sub>6</sub>H<sub>5</sub>)2PCH<sub>2</sub>CH<sub>2</sub>}3NNiCO

Synonyms:{(C₆H₅)2PCH₂CH₂}3NNiCO

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Chemical Property of {(C₆H₅)2PCH₂CH₂}3NNiCO

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Technology Process of {(C₆H₅)2PCH₂CH₂}3NNiCO

There total 4 articles about {(C₆H₅)2PCH₂CH₂}3NNiCO which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 52633-73-5,97135-31-4
(tris(2-diphenylphosphinoethyl)amine)nickel⁽⁰⁾

: 88440-32-8
{(C₆H₅)2PCH₂CH₂}3NNiCO

Guidance literature:: With COS; In tetrahydrofuran; bubbling COS for ca. 2 min through a soln. of (np3)Ni in THF; adding n-butanol and evapg. the solvent; washing with ethanol and petroleum ether (b.p.40-70°C); drying in stream of nitrogen; elem. anal.;
DOI:10.1016/0022-328X(84)80366-6

Reference yield: 85.0%

: 52633-73-5,97135-31-4
(tris(2-diphenylphosphinoethyl)amine)nickel⁽⁰⁾

: 88440-32-8
{(C₆H₅)2PCH₂CH₂}3NNiCO

: 151866-22-7
{Ni(CO)2(P(C₆H₅)2CH₂CH₂N(CH₂CH₂P(C₆H₅)2)CH₂CH₂P(C₆H₅)2)}

Guidance literature:: With carbon monoxide; In tetrahydrofuran; react. in an autoclave; 1 atm CO, 20°C, 1 h; filtn., washed with ethanol, recrystn. (THF/ETOH), elem. anal.;
DOI:10.1021/om00036a015

Reference yield: 80.0%

: 95099-93-7
(N(CH₂CH₂P(C₆H₅)2)3)Ni(CO₂C₂H₅)⁽¹⁺⁾*B(C₆H₅)4^(1-)=[(N(CH₂CH₂P(C₆H₅)2)3)Ni(CO₂C₂H₅)]B(C₆H₅)4

: 88440-32-8
{(C₆H₅)2PCH₂CH₂}3NNiCO

Guidance literature:: With lithium triethylborohydride; In tetrahydrofuran; (N2); complex soln. in THF treated with soln. of LiHBEt3 in THF; pptd. (butanol);
DOI:10.1016/0022-328X(84)80663-4