Ru₃(CO)11PMe₂Ph

Base Information

• Chemical Name: Ru₃(CO)11PMe₂Ph
• CAS No.: 38686-57-6
• Molecular Formula: C₁₉H₁₁O₁₁PRu₃
• Molecular Weight: 749.474
• Mol file: 38686-57-6.mol

Synonyms:Ru₃(CO)11PMe₂Ph

Chemical Property of Ru₃(CO)11PMe₂Ph

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of Ru₃(CO)11PMe₂Ph

There total 1 articles about Ru₃(CO)11PMe₂Ph which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

dodecacarbonyl-triangulo-triruthenium (15243-33-1) + Dimethyl(phenyl)phosphine (672-66-2) → Ru3(CO)11PMe2Ph (38686-57-6)

Guidance literature:

With sodium diphenylketyl; In tetrahydrofuran; a THF soln. of Ph2CONa was added dropwise under N2 to a soln. of Ru3(CO)12 and PMe2Ph in 1:1 molar ratio in THF, reaction was monitored by IR spectroscopy; THF was pumped off under vac., residue recrystd. from warm light petroleum; elem. anal.;

DOI:10.1016/0022-328X(83)85174-2

Reference yield: 42.0%

Ru3(CO)11PMe2Ph (38686-57-6) + tert-butylisonitrile (119072-55-8,7188-38-7) → Ru3(CO)10(P(CH3)2C6H5)(CNC(CH3)3) (84330-39-2)

Guidance literature:

With sodium diphenylketyl; In tetrahydrofuran; addn. of soln. of sodium diphenylketyl (0.01 M soln. in THF) to equimolar mixt. of educts in THF, room temp., 5 min;

DOI:10.1016/S0022-328X(00)86919-3

upstream raw materials:

dodecacarbonyl-triangulo-triruthenium

Dimethyl(phenyl)phosphine

Downstream raw materials:

Ru₃(CO)10(P(CH₃)2C₆H₅)(CNC(CH₃)3)