phenyl [3,4-di-O-benzyl-2-O-(p-methoxybenzyl)-α-L-rhamnopyranosyl]-(1→3)-2,3,6-tribenzyl-1-thio-β-D-glucopyranoside

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Chemical Name:phenyl [3,4-di-O-benzyl-2-O-(p-methoxybenzyl)-α-L-rhamnopyranosyl]-(1→3)-2,3,6-tribenzyl-1-thio-β-D-glucopyranoside
CAS No.:1437303-56-4
Molecular Formula:C₆₁H₆₄O₁₀S
Molecular Weight:989.239
Hs Code.:

Synonyms:phenyl [3,4-di-O-benzyl-2-O-(p-methoxybenzyl)-α-L-rhamnopyranosyl]-(1→3)-2,3,6-tribenzyl-1-thio-β-D-glucopyranoside

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Chemical Property of phenyl [3,4-di-O-benzyl-2-O-(p-methoxybenzyl)-α-L-rhamnopyranosyl]-(1→3)-2,3,6-tribenzyl-1-thio-β-D-glucopyranoside

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Technology Process of phenyl [3,4-di-O-benzyl-2-O-(p-methoxybenzyl)-α-L-rhamnopyranosyl]-(1→3)-2,3,6-tribenzyl-1-thio-β-D-glucopyranoside

There total 5 articles about phenyl [3,4-di-O-benzyl-2-O-(p-methoxybenzyl)-α-L-rhamnopyranosyl]-(1→3)-2,3,6-tribenzyl-1-thio-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 1437303-55-3
phenyl [3,4-di-O-benzyl-2-O-(p-methoxybenzyl)-α-L-rhamnopyranosyl]-(1→3)-2,3,6-tri-benzoyl-1-thio-β-D-glucopyranoside

: 100-39-0
benzyl bromide

: 1437303-56-4
phenyl [3,4-di-O-benzyl-2-O-(p-methoxybenzyl)-α-L-rhamnopyranosyl]-(1→3)-2,3,6-tribenzyl-1-thio-β-D-glucopyranoside

Guidance literature:: With tetrabutylammomium bromide; sodium hydroxide; In N,N-dimethyl-formamide; at 20 ℃; for 5h;
DOI:10.1016/j.tetasy.2013.04.001

Reference yield:

: 138857-50-8
phenyl 2,3-bis-O-benzoyl-1-thio-β-D-glucopyranoside

: 1437303-56-4
phenyl [3,4-di-O-benzyl-2-O-(p-methoxybenzyl)-α-L-rhamnopyranosyl]-(1→3)-2,3,6-tribenzyl-1-thio-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: pyridine / dichloromethane / 0 - 20 °C

2: N-iodo-succinimide; trimethylsilyl trifluoromethanesulfonate / dichloromethane / 1 h / -35 °C / Inert atmosphere; Molecular sieve

3: sodium hydroxide; tetrabutylammomium bromide / N,N-dimethyl-formamide / 5 h / 20 °C

With pyridine; N-iodo-succinimide; trimethylsilyl trifluoromethanesulfonate; tetrabutylammomium bromide; sodium hydroxide; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/j.tetasy.2013.04.001

Reference yield:

: 613-90-1
benzoyl cyanide

: 1437303-56-4
phenyl [3,4-di-O-benzyl-2-O-(p-methoxybenzyl)-α-L-rhamnopyranosyl]-(1→3)-2,3,6-tribenzyl-1-thio-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: pyridine / dichloromethane / 0 - 20 °C

2: N-iodo-succinimide; trimethylsilyl trifluoromethanesulfonate / dichloromethane / 1 h / -35 °C / Inert atmosphere; Molecular sieve

3: sodium hydroxide; tetrabutylammomium bromide / N,N-dimethyl-formamide / 5 h / 20 °C

With pyridine; N-iodo-succinimide; trimethylsilyl trifluoromethanesulfonate; tetrabutylammomium bromide; sodium hydroxide; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/j.tetasy.2013.04.001