[bis(N-(2,6-diisopropylphenyl)iminobenzyl-κN,N')pyridine-κN]FeCl2

Base Information

Chemical Name:[bis(N-(2,6-diisopropylphenyl)iminobenzyl-κN,N')pyridine-κN]FeCl2
CAS No.:301658-91-3
Molecular Formula:C₄₃H₄₇Cl₂FeN₃
Molecular Weight:732.619
Hs Code.:

Synonyms:[bis(N-(2,6-diisopropylphenyl)iminobenzyl-κN,N')pyridine-κN]FeCl2

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Chemical Property of [bis(N-(2,6-diisopropylphenyl)iminobenzyl-κN,N')pyridine-κN]FeCl2

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Technology Process of [bis(N-(2,6-diisopropylphenyl)iminobenzyl-κN,N')pyridine-κN]FeCl2

There total 2 articles about [bis(N-(2,6-diisopropylphenyl)iminobenzyl-κN,N')pyridine-κN]FeCl2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: bis(2,6-diisopropylphenyliminobenzyl)pyridine

: iron(II) chloride

: 301658-91-3
[bis(N-(2,6-diisopropylphenyl)iminobenzyl-κN,N')pyridine-κN]FeCl2

Guidance literature:: In butan-1-ol; Schlenk flasks contg. FeCl2/n-BuOH and ligand/n-BuOH heated to 80°C for 1 h, the Fe salt soln. transferred under Ar to the suspn. of ligand, heated for 30 min at 80°C, stirred for 12 h at room temp.; evapd. (vac.), washed (pentane), filtered, dried (vac.); elem. anal.;
DOI:10.1021/ja052129k

Reference yield: 70.0%

: 5768-24-1
2,6-dibenzoylpyridine

: 24544-04-5
2,6-diisopropylbenzenamine

: iron(II) chloride

: 301658-91-3
[(2,6-(2,6-(i-Pr)2-C₆H₃N=CPh)2C₅H₃N)FeCl₂]

Guidance literature:: In acetic acid; (N2); std. Schlenk technique; soln. of aniline in acetic acid was added to dibenzoylpyridine; soln. was refluxed; FeCl2 was added with stirring;refluxed for 4 h; cooled to room temp.; acid removed (vac., Schlenk line); solvent removed(vac.); dissolved in CH2Cl2 in drybox; layered with pentane; filtered; filter cake washed (Et2O, pentane); dried (vac.); elem. anal.;
DOI:10.1021/om060441c

Reference yield: 40.0%

: 301658-91-3
[(2,6-(2,6-(i-Pr)2-C₆H₃N=CPh)2C₅H₃N)FeCl₂]

: 7727-37-9
nitrogen

: 910818-17-6
[(2,6-(2,6-(i-Pr)2-C₆H₃N=CPh)2C₅H₃N)Fe(N₂)2]

Guidance literature:: With Hg; Na; In pentane; (N2); Schlenk technique; Na added to Hg in pentane; suspn. stirred for 15 min; suspn. of Fe complex/pentane added; sealed; cooled to liq. N2 temp.; evacuated; N2 (4 atm) added at -196°C; resealed; warmed to ambient temp.; stirred for 24 h; decanted; extd. (pentane); filtered through Celite; solvent from combined org. layers removed (vac.); recrystd. (pentane, -35°C); elem. anal.;
DOI:10.1021/om060441c