But-3-enyl-{(S)-1-[(E)-2-((1S,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-vinyl]-butyl}-carbamic acid tert-butyl ester

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Chemical Name:But-3-enyl-{(S)-1-[(E)-2-((1S,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-vinyl]-butyl}-carbamic acid tert-butyl ester
CAS No.:868745-25-9
Molecular Formula:C₂₅H₄₅NO₂
Molecular Weight:391.638
Hs Code.:

Synonyms:But-3-enyl-{(S)-1-[(E)-2-((1S,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-vinyl]-butyl}-carbamic acid tert-butyl ester

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Chemical Property of But-3-enyl-{(S)-1-[(E)-2-((1S,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-vinyl]-butyl}-carbamic acid tert-butyl ester

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Technology Process of But-3-enyl-{(S)-1-[(E)-2-((1S,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-vinyl]-butyl}-carbamic acid tert-butyl ester

There total 6 articles about But-3-enyl-{(S)-1-[(E)-2-((1S,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-vinyl]-butyl}-carbamic acid tert-butyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 868745-24-8
But-3-enyl-{(S)-1-[(E)-2-((1S,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-vinyl]-butyl}-amine

: 24424-99-5
di-tert-butyl dicarbonate

: 868745-25-9
But-3-enyl-{(S)-1-[(E)-2-((1S,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-vinyl]-butyl}-carbamic acid tert-butyl ester

Guidance literature:: With triethylamine; In N,N-dimethyl-formamide; at 60 ℃; for 6h;
DOI:10.1021/ol052034n

Reference yield:

: 66703-03-5
trans-1-iodo-1-pentene

: 868745-25-9
But-3-enyl-{(S)-1-[(E)-2-((1S,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-vinyl]-butyl}-carbamic acid tert-butyl ester

Guidance literature:: Multi-step reaction with 5 steps

1.1: t-BuLi / diethyl ether; pentane / 2.5 h / -78 - 20 °C

1.2: AlMe₃ / diethyl ether; pentane; hexane / 3 h / -78 °C

2.1: 80 percent / HN₃; DEAD; PPh₃ / benzene / 6 h / 0 - 20 °C

3.1: LiAlH₄ / tetrahydrofuran / 0.5 h / 20 °C

4.1: 67 percent / CsOH*H₂O / dimethylformamide / 106 h / 20 °C

5.1: 100 percent / Et₃N / dimethylformamide / 6 h / 60 °C

With cesium hydroxide; lithium aluminium tetrahydride; tris-(2-chloro-ethyl)-amine; tert.-butyl lithium; triethylamine; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; diethyl ether; N,N-dimethyl-formamide; pentane; benzene; 2.1: Mitsunobu reaction;
DOI:10.1021/ol052034n

Reference yield:

: 80434-59-9,485843-44-5,796865-68-4
(1R,2S,5R)-2-isopropyl-5-methylcyclohexanecarboxaldehyde

: 868745-25-9
But-3-enyl-{(S)-1-[(E)-2-((1S,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-vinyl]-butyl}-carbamic acid tert-butyl ester

Guidance literature:: Multi-step reaction with 5 steps

1.1: t-BuLi / diethyl ether; pentane / 2.5 h / -78 - 20 °C

1.2: AlMe₃ / diethyl ether; pentane; hexane / 3 h / -78 °C

2.1: 80 percent / HN₃; DEAD; PPh₃ / benzene / 6 h / 0 - 20 °C

3.1: LiAlH₄ / tetrahydrofuran / 0.5 h / 20 °C

4.1: 67 percent / CsOH*H₂O / dimethylformamide / 106 h / 20 °C

5.1: 100 percent / Et₃N / dimethylformamide / 6 h / 60 °C

With cesium hydroxide; lithium aluminium tetrahydride; tris-(2-chloro-ethyl)-amine; tert.-butyl lithium; triethylamine; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; diethyl ether; N,N-dimethyl-formamide; pentane; benzene; 2.1: Mitsunobu reaction;
DOI:10.1021/ol052034n