triscarbonyl-(η⁴-3,4-bis(4-methoxyphenyl)-2,5-diphenylcyclopenta-2,4-dienone)iron

Base Information

• Chemical Name: triscarbonyl-(η⁴-3,4-bis(4-methoxyphenyl)-2,5-diphenylcyclopenta-2,4-dienone)iron
• CAS No.: 33504-08-4
• Molecular Formula: C₃₂H₂₀FeO₄
• Molecular Weight: 524.355
• Mol file: 33504-08-4.mol

Synonyms:triscarbonyl-(η⁴-3,4-bis(4-methoxyphenyl)-2,5-diphenylcyclopenta-2,4-dienone)iron

Chemical Property of triscarbonyl-(η⁴-3,4-bis(4-methoxyphenyl)-2,5-diphenylcyclopenta-2,4-dienone)iron

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of triscarbonyl-(η⁴-3,4-bis(4-methoxyphenyl)-2,5-diphenylcyclopenta-2,4-dienone)iron

There total 9 articles about triscarbonyl-(η⁴-3,4-bis(4-methoxyphenyl)-2,5-diphenylcyclopenta-2,4-dienone)iron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

triiron dodecarbonyl (17685-52-8) + 2,3,4,5-tetraphenylcyclopenta-2,4-dienone (479-33-4) → tricarbonyl(tetraphenylcyclopentadienone)iron (33504-08-4)

Guidance literature:

In toluene; (inert atm.); dissolving Fe compd. and Ph4C5O in toluene, heating at 80°C in sealed tube for 20 h; cooling to room temp., evapn. under reduced pressure, dissolving in EtOAc, filtration (Celite), evapn. under reduced pressure;

DOI:10.1021/om101101r

Reference yield: 86.0%

triiron dodecarbonyl (17685-52-8) + 2,3,4,5-tetraphenylcyclopenta-2,4-dienone (479-33-4) → triscarbonyl-(η4-3,4-bis(4-methoxyphenyl)-2,5-diphenylcyclopenta-2,4-dienone)iron (33504-08-4)

Guidance literature:

In toluene; at 80 ℃; for 20h; Inert atmosphere; Schlenk technique;

Reference yield: 83.0%

diiron nonacarbonyl (15321-51-4) + 2,3,4,5-tetraphenylcyclopenta-2,4-dienone (479-33-4) → triscarbonyl-(η4-3,4-bis(4-methoxyphenyl)-2,5-diphenylcyclopenta-2,4-dienone)iron (33504-08-4)

Guidance literature:

In toluene; at 110 ℃; for 16h; Inert atmosphere; Sealed tube;

DOI:10.1021/jacs.8b08596

upstream raw materials:

iron pentacarbonyl

4,5,6,7-tetraphenyl-3a,4,7,7a-tetrahydro-4,7-methanoinden-8-one

triiron dodecarbonyl

2,3,4,5-tetraphenylcyclopenta-2,4-dienone

Downstream raw materials:

2,3,4,5-tetraphenylcyclopenta-2,4-dienone

triiron dodecarbonyl

dicarbonyl(η4-tetraphenylcyclopentadienone)(trimethyl phosphite)iron