trans-chlorobis(triethylphosphine)(p-trifluoromethylphenyl)platinum(II)

Base Information

• Chemical Name: trans-chlorobis(triethylphosphine)(p-trifluoromethylphenyl)platinum(II)
• CAS No.: 67049-38-1
• Molecular Formula: C₁₉H₃₄ClF₃P₂Pt
• Molecular Weight: 611.955
• Mol file: 67049-38-1.mol

Synonyms:trans-chlorobis(triethylphosphine)(p-trifluoromethylphenyl)platinum(II)

Chemical Property of trans-chlorobis(triethylphosphine)(p-trifluoromethylphenyl)platinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of trans-chlorobis(triethylphosphine)(p-trifluoromethylphenyl)platinum(II)

There total 19 articles about trans-chlorobis(triethylphosphine)(p-trifluoromethylphenyl)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

trans,cis-platinum(triethylphosphine)2(4-trifluoromethylphenyl)(bromo)2(chloride) → trans-chlorobis(triethylphosphine)(p-trifluoromethylphenyl)platinum(II) (67049-38-1) + trans-PtBr(C6H4-p-CF3)(PEt3)2

Guidance literature:

With 2,3-Dimethyl-2-butene; In benzene-d6; Inert atmosphere; Sealed tube; Irradiation;

DOI:10.1021/ic5009413

Reference yield: 73.0%

trans,cis-platinum(triethylphosphine)2(4-trifluoromethylphenyl)(chloro)2(bromide) → trans-chlorobis(triethylphosphine)(p-trifluoromethylphenyl)platinum(II) (67049-38-1) + trans-PtBr(C6H4-p-CF3)(PEt3)2

Guidance literature:

With 1-hexene; In benzene-d6; Reagent/catalyst; Inert atmosphere; Sealed tube; Irradiation;

DOI:10.1021/ic5009413

Reference yield: 63.0%

tetrakis(triethylphosphine)platinum(0) (33937-26-7) + 4-chlorobenzotrifluoride (98-56-6) → trans-chlorobis(triethylphosphine)(p-trifluoromethylphenyl)platinum(II) (67049-38-1)

Guidance literature:

In tetrahydrofuran; at 140 ℃; for 20h; Sealed tube;

DOI:10.1021/ic402358s

upstream raw materials:

chloroform-d1

trans,cis-Pt-(PEt₃)₂(Cl)₂(OH)(4-trifluoromethylphenyl)

dichloromethane-d2

trans-Pt(PEt₃)₂(Br)(Cl)(OH)(4-trifluoromethylphenyl)

Downstream raw materials:

trans-Pt(PEt₃)₂Cl(OH)(OOH)(4-trifluoromethylphenyl)

C₁₉H₃₄Cl₃F₃P₂Pt