N,N-bis(4'-diphenylamino-4-biphenylyl)amine

Base Information

• Chemical Name: N,N-bis(4'-diphenylamino-4-biphenylyl)amine
• CAS No.: 167218-39-5
• Molecular Formula: C₄₈H₃₇N₃
• Molecular Weight: 655.842
• Mol file: 167218-39-5.mol

Synonyms:N,N-bis(4'-diphenylamino-4-biphenylyl)amine

Chemical Property of N,N-bis(4'-diphenylamino-4-biphenylyl)amine

Chemical Property:

• Melting Point: 211 °C
• Boiling Point: 807.1±65.0 °C(Predicted)
• PKA: 1.03±0.50(Predicted)
• Density: 1.195±0.06 g/cm3(Predicted)
• Solubility.: soluble in Toluene

Purity/Quality:

97% ^*data from raw suppliers

N,N-Bis(4'-diphenylamino-4-biphenylyl)amine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N-bis(4'-diphenylamino-4-biphenylyl)amine

There total 1 articles about N,N-bis(4'-diphenylamino-4-biphenylyl)amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

bis(4-bromophenyl)amine (16292-17-4) + 4-(diphenylamino)phenyl boronic acid (201802-67-7) → N,N-bis(4'-diphenylamino-4-biphenylyl)amine (167218-39-5)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate; In water; toluene; at 110 ℃; for 48h; Inert atmosphere;

DOI:10.1021/cm202732j

Reference yield: 90.0%

N,N-bis(4'-diphenylamino-4-biphenylyl)amine (167218-39-5) + 1,4-bromoiodobenzene (589-87-7) → C54H40BrN3 (1352129-73-7)

Guidance literature:

With copper(l) iodide; trans-1,2-Diaminocyclohexane; potassium tert-butylate; In 1,4-dioxane; at 110 ℃; chemoselective reaction; Inert atmosphere; Large scale reaction;

DOI:10.1021/cm202732j

Reference yield: 60.0%

N,N-bis(4'-diphenylamino-4-biphenylyl)amine (167218-39-5) + 1,3,5-tris(4-bromophenyl)benzene (7511-49-1) → 1,3,5-tris{4-[N,N-bis(4'-diphenylaminobiphenyl-4-yl)]aminophenyl}benzene

Guidance literature:

With sodium t-butanolate; palladium diacetate; tri-tert-butyl phosphine; In toluene; at 60 ℃; for 9h; Heating / reflux;

upstream raw materials:

bis(4-bromophenyl)amine

4-(diphenylamino)phenyl boronic acid

Downstream raw materials:

C₅₄H₄₀BrN₃

C₆₀H₅₂BN₃O₂