BIS(4-BROMOPHENYL)AMINE

Base Information

• Chemical Name: BIS(4-BROMOPHENYL)AMINE
• CAS No.: 16292-17-4
• Molecular Formula: C12H9Br2N
• Molecular Weight: 327.018
• Hs Code.: 29214400
• Mol file: 16292-17-4.mol

Synonyms:Diphenylamine,4,4'-dibromo- (6CI,7CI,8CI);4,4'-Dibromodiphenylamine;Bis(4-bromophenyl)amine;Bis(p-bromophenyl)amine;N-Phenyl-4,4'-dibromoaniline;

Chemical Property of BIS(4-BROMOPHENYL)AMINE

Chemical Property:

• Vapor Pressure: 5.42E-06mmHg at 25°C
• Melting Point: 106 °C
• Refractive Index: 1.68
• Boiling Point: 380.5 °C at 760 mmHg
• PKA: -0.55±0.40(Predicted)
• Flash Point: 183.9 °C
• PSA: 12.03000
• Density: 1.74 g/cm³
• LogP: 5.02820
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• Solubility.: soluble in Methanol

Purity/Quality:

98% ^*data from raw suppliers

Bis(4-Bromophenyl)amine ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 22-41
• Safety Statements: 26-36/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of BIS(4-BROMOPHENYL)AMINE

There total 25 articles about BIS(4-BROMOPHENYL)AMINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

N,N-bis-(4-bromophenyl)benzamide (99234-92-1) → bis(4-bromophenyl)amine (16292-17-4)

Guidance literature:

With potassium hydroxide; In tetrahydrofuran; methanol; water; at 0 - 70 ℃; for 12h;

DOI:10.1080/00397911.2014.894527

Reference yield: 94.0%

C19H15Br2NO2S → bis(4-bromophenyl)amine (16292-17-4)

Guidance literature:

With trifluorormethanesulfonic acid; In 1,2-dichloro-ethane; at 25 - 90 ℃; for 50h; Inert atmosphere;

DOI:10.1021/acs.joc.7b02507

Reference yield: 92.0%

4-Bromophenylboronic acid (5467-74-3) + 4-bromo-aniline (106-40-1) → bis(4-bromophenyl)amine (16292-17-4)

Guidance literature:

With copper immobilized at polyimide covalent organic framework; In methanol; water; at 20 ℃; for 8h;

DOI:10.1039/c8gc02611d

upstream raw materials:

N,N-bis-(4-bromophenyl)benzamide

diphenylamine

N-nitrosodiphenylamine

N(C₆H₄Br)2

Downstream raw materials:

4,4'-dibromodiphenylnitrosamine

4-bromo-N-(4-bromophenyl)-N-(4-nitrophenyl)amine

N-butylbis(4-bromophenyl)amine

N-heptylbis(4-bromophenyl)amine

Refernces

• 1、 Yan, Mao,Wang, Qun-Hui,Zhu, Yi-Zhou,Han, Ming-Liang,Yan, Yi-Qiao,Zheng, Jian-Yu. "Effect of triptycene unit on the performance of porphyrin-based dye-sensitized solar cells". . . Retrieved 2021.
• 2、 Gavat, Odile,Giuseppone, Nicolas,Lehn, Jean-Marie,Maaloum, Mounir,Moulin, Emilie,Picini, Flavio,Schneider, Susanne,Strub, Jean-Marc,Tan, Junjun,Tokunaga, Shoichi,Vargas Jentzsch, Andreas. "Supramolecular Polymerization of Triarylamine-Based Macrocycles into Electroactive Nanotubes". supporting information. p. 6498 - 6504. Retrieved 2021/05/06.