ethyl 2,3,4-tri-O-benzoyl-6-O-levulinyl-1-thio-β-D-glucopyranoside

Base Information

• Chemical Name: ethyl 2,3,4-tri-O-benzoyl-6-O-levulinyl-1-thio-β-D-glucopyranoside
• CAS No.: 615570-67-7
• Molecular Formula: C₃₄H₃₄O₁₀S
• Molecular Weight: 634.704
• Mol file: 615570-67-7.mol

Synonyms:ethyl 2,3,4-tri-O-benzoyl-6-O-levulinyl-1-thio-β-D-glucopyranoside

Chemical Property of ethyl 2,3,4-tri-O-benzoyl-6-O-levulinyl-1-thio-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ethyl 2,3,4-tri-O-benzoyl-6-O-levulinyl-1-thio-β-D-glucopyranoside

There total 1 articles about ethyl 2,3,4-tri-O-benzoyl-6-O-levulinyl-1-thio-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

ethyl 2,3,4-tri-O-benzoyl-1-thio-β-D-glucopyranoside (35784-51-1) + levulinic acid (123-76-2) → ethyl 2,3,4-tri-O-benzoyl-6-O-levulinyl-1-thio-β-D-glucopyranoside (615570-67-7)

Guidance literature:

With dmap; dicyclohexyl-carbodiimide; In dichloromethane; for 16h;

DOI:10.1021/ol0352355

Reference yield: 72.0%

4-allyloxybenzyl alcohol (3256-45-9) + ethyl 2,3,4-tri-O-benzoyl-6-O-levulinyl-1-thio-β-D-glucopyranoside (615570-67-7) → p-(allyloxy)benzyl 2,3,4-tri-O-benzoyl-6-O-levulinyl-β-D-glucopyranoside (615570-73-5)

Guidance literature:

With N-iodo-succinimide; trimethylsilyl trifluoromethanesulfonate; 4 A molecular sieve; In dichloromethane; at 0 ℃;

DOI:10.1021/ol0352355

Reference yield: 24.0%

ethyl 2,3,4-tri-O-benzoyl-6-O-levulinyl-1-thio-β-D-glucopyranoside (615570-67-7) + p-[p-(4-arm branched polyethylene glycol)oxy-benzoyloxy]benzyl 2,3,4-tri-O-benzoyl-6-O-levulinyl-β-D-glucopyranoside → 4-hydroxybenzyl 2,3,4-tri-O-benzoyl-β-D-(1-6)-glucopyranosyl-2,3,4-tri-O-benzoyl-β-D-(1-6)-glucopyranosyl-2,3,4-tri-O-benzoyl-β-D-(1-6)-glucopyranosyl-2,3,4-tri-O-benzoyl-β-D-glucopyranoside

Guidance literature:

Multistep reaction;

DOI:10.1021/ol0352355

upstream raw materials:

ethyl 2,3,4-tri-O-benzoyl-1-thio-β-D-glucopyranoside

levulinic acid

Downstream raw materials:

p-(allyloxy)benzyl 2,3,4-tri-O-benzoyl-6-O-levulinyl-β-D-glucopyranoside

p-hydroxybenzyl 2,3,4-tri-O-benzoyl-6-O-levulinyl-β-D-glucopyranoside