1-(4-nitrophenyl)-2-(phenylselanyl)-2-(triphenylphosphaneylidene)ethan-1-one

Base Information

• Chemical Name: 1-(4-nitrophenyl)-2-(phenylselanyl)-2-(triphenylphosphaneylidene)ethan-1-one
• CAS No.: 91585-41-0
• Molecular Formula: C₃₂H₂₄NO₃PSe
• Molecular Weight: 580.481
• Mol file: 91585-41-0.mol

Synonyms:1-(4-nitrophenyl)-2-(phenylselanyl)-2-(triphenylphosphaneylidene)ethan-1-one

Chemical Property of 1-(4-nitrophenyl)-2-(phenylselanyl)-2-(triphenylphosphaneylidene)ethan-1-one

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-(4-nitrophenyl)-2-(phenylselanyl)-2-(triphenylphosphaneylidene)ethan-1-one

There total 3 articles about 1-(4-nitrophenyl)-2-(phenylselanyl)-2-(triphenylphosphaneylidene)ethan-1-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

p-tolyl benzeneselenosulfonate (68819-94-3) + (4'-nitrophenacyl)triphenylphosphonium bromide (17730-93-7) → 1-(4-nitrophenyl)-2-(phenylselanyl)-2-(triphenylphosphaneylidene)ethan-1-one (91585-41-0)

Guidance literature:

With triethylamine; In dichloromethane; at 25 ℃; for 0.3h;

DOI:10.1021/acs.joc.1c00114

Reference yield: 66.0%

Phenylselenyl bromide (34837-55-3) + 1-(4-nitro-phenyl)-2-(triphenyl-λ5-phosphanylidene)-ethanone (1439-43-6) → 1-(4-nitrophenyl)-2-(phenylselanyl)-2-(triphenylphosphaneylidene)ethan-1-one (91585-41-0)

Guidance literature:

In benzene; for 2h; Ambient temperature;

DOI:10.1055/s-1984-30789

Reference yield:

diphenyl diselenide (1666-13-3) → 1-(4-nitrophenyl)-2-(phenylselanyl)-2-(triphenylphosphaneylidene)ethan-1-one (91585-41-0)

Guidance literature:

Multi-step reaction with 2 steps

1: N-Bromosuccinimide / acetonitrile / 2 h

2: triethylamine / dichloromethane / 0.3 h / 25 °C

With N-Bromosuccinimide; triethylamine; In dichloromethane; acetonitrile;

DOI:10.1021/acs.joc.1c00114

upstream raw materials:

Phenylselenyl bromide

1-(4-nitro-phenyl)-2-(triphenyl-λ⁵-phosphanylidene)-ethanone

p-tolyl benzeneselenosulfonate

(4'-nitrophenacyl)triphenylphosphonium bromide

Downstream raw materials:

1-Nitro-4-phenylselanylethynyl-benzene