chloro[2-(hydroxymethyl-κO)benzyl-κC(1α)](triphenylphosphine)palladium

Base Information

Chemical Name:chloro[2-(hydroxymethyl-κO)benzyl-κC(1α)](triphenylphosphine)palladium
CAS No.:849417-34-1
Molecular Formula:C₂₆H₂₄ClOPPd
Molecular Weight:525.323
Hs Code.:

Synonyms:chloro[2-(hydroxymethyl-κO)benzyl-κC(1α)](triphenylphosphine)palladium

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Chemical Property of chloro[2-(hydroxymethyl-κO)benzyl-κC(1α)](triphenylphosphine)palladium

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Technology Process of chloro[2-(hydroxymethyl-κO)benzyl-κC(1α)](triphenylphosphine)palladium

There total 1 articles about chloro[2-(hydroxymethyl-κO)benzyl-κC(1α)](triphenylphosphine)palladium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 14221-01-3
tetrakis(triphenylphosphine) palladium⁽⁰⁾

: 142066-41-9
2-(chloromethyl)-phenyl methanol

: 849417-34-1
chloro[2-(hydroxymethyl-κO)benzyl-κC(1α)](triphenylphosphine)palladium

Guidance literature:: In toluene; (N2); Schlenk technique; soln. of ligand (1 equiv.) in toluene was addeddropwise to stirred suspn. of Pd complex (1 equiv.) in toluene; mixt. w as stirred at room temp. for 12 h; filtered; washed (Et2O); dried (vac.); crystd. (CH2Cl2/petroleum ether);elem. anal.;
DOI:10.1021/om049131p

Reference yield: 85.0%

: 849417-34-1
chloro[2-(hydroxymethyl-κO)benzyl-κC(1α)](triphenylphosphine)palladium

: 201230-82-2
carbon monoxide

: 849417-40-9
chloro[2-(hydroxymethyl-κO)phenylacetyl-κC(1β)](triphenylphosphine)palladium

Guidance literature:: In tetrahydrofuran; (N2); Schlenk technique; CO (1 atm) was bubbled through soln. of Pd complex in THF for 20 min; petroleum ether quickly added; cooled to -78°C; filtered;
DOI:10.1021/om049131p

Reference yield: 77.0%

: 849417-34-1
chloro[2-(hydroxymethyl-κO)benzyl-κC(1α)](triphenylphosphine)palladium

: 7732-18-5
water

: bis[2-(μ-oxomethyl-κO)benzyl-κC(1α)](triphenylphosphine)dipalladium monohydrate

Guidance literature:: With NaH; PPh₃; In tetrahydrofuran; byproducts: NaCl, H2; (N2); Schlenk technique; NaH (1 equiv.) in mineral oil was added to suspn. of Pd complex and PPh3 in THF; suspn. was stirred at room temp. for 12 h; filtered; washed (H2O, Et2O); dried (vac.); recrystd. (CH2Cl2/petroleum ether); elem. anal.;
DOI:10.1021/om049131p