4',6'-O-benzylidene-1'-O-methyl-2'-deoxy-2'-(adenin-9-yl)-D-altropyranoside

Base Information

Chemical Name:4',6'-O-benzylidene-1'-O-methyl-2'-deoxy-2'-(adenin-9-yl)-D-altropyranoside
CAS No.:151909-23-8
Molecular Formula:C₁₉H₂₁N₅O₅
Molecular Weight:399.406
Hs Code.:

Synonyms:4',6'-O-benzylidene-1'-O-methyl-2'-deoxy-2'-(adenin-9-yl)-D-altropyranoside

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Chemical Property of 4',6'-O-benzylidene-1'-O-methyl-2'-deoxy-2'-(adenin-9-yl)-D-altropyranoside

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Technology Process of 4',6'-O-benzylidene-1'-O-methyl-2'-deoxy-2'-(adenin-9-yl)-D-altropyranoside

There total 5 articles about 4',6'-O-benzylidene-1'-O-methyl-2'-deoxy-2'-(adenin-9-yl)-D-altropyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 66224-66-6,66224-67-7,66224-68-8,66224-69-9,134434-48-3,134434-49-4,134454-76-5,134461-75-9
adenine

: 66537-92-6
methyl 2,3-anhydro-4,6-benzylidene-α-D-allopyranoside

: 151909-23-8
4',6'-O-benzylidene-1'-O-methyl-2'-deoxy-2'-(adenin-9-yl)-D-altropyranoside

Guidance literature:: adenine; With sodium hydride; In N,N-dimethyl-formamide; mineral oil; at 90 ℃; for 1h; Inert atmosphere;

methyl 2,3-anhydro-4,6-benzylidene-α-D-allopyranoside; In N,N-dimethyl-formamide; mineral oil; at 120 ℃; regioselective reaction; Inert atmosphere;
DOI:10.3390/molecules20034020

Reference yield:

: 97-30-3
methyl-alpha-D-glucopyranoside

: 151909-23-8
4',6'-O-benzylidene-1'-O-methyl-2'-deoxy-2'-(adenin-9-yl)-D-altropyranoside

Guidance literature:: Multi-step reaction with 4 steps

1.1: zinc(II) chloride / 72 h

2.1: pyridine / 72 h / 60 °C

3.1: sodium methylate / dichloromethane; methanol / 12 h / 20 °C

4.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 1 h / 90 °C / Inert atmosphere

4.2: 120 °C / Inert atmosphere

With pyridine; sodium methylate; sodium hydride; zinc(II) chloride; In methanol; dichloromethane; N,N-dimethyl-formamide; mineral oil;
DOI:10.3390/molecules20034020

Reference yield:

: 100-52-7
benzaldehyde

: 151909-23-8
4',6'-O-benzylidene-1'-O-methyl-2'-deoxy-2'-(adenin-9-yl)-D-altropyranoside

Guidance literature:: Multi-step reaction with 4 steps

1.1: zinc(II) chloride / 72 h

2.1: pyridine / 72 h / 60 °C

3.1: sodium methylate / dichloromethane; methanol / 12 h / 20 °C

4.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 1 h / 90 °C / Inert atmosphere

4.2: 120 °C / Inert atmosphere

With pyridine; sodium methylate; sodium hydride; zinc(II) chloride; In methanol; dichloromethane; N,N-dimethyl-formamide; mineral oil;
DOI:10.3390/molecules20034020