2-methyl-1-phenylbuta-2,3-dien-1-yl benzoate

Base Information

• Chemical Name: 2-methyl-1-phenylbuta-2,3-dien-1-yl benzoate
• CAS No.: 1394905-07-7
• Molecular Formula: C₁₈H₁₆O₂
• Molecular Weight: 264.324
• Mol file: 1394905-07-7.mol

Synonyms:2-methyl-1-phenylbuta-2,3-dien-1-yl benzoate

Chemical Property of 2-methyl-1-phenylbuta-2,3-dien-1-yl benzoate

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of 2-methyl-1-phenylbuta-2,3-dien-1-yl benzoate

There total 1 articles about 2-methyl-1-phenylbuta-2,3-dien-1-yl benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

2-methyl-1-phenylbuta-2,3-dien-1-ol (78808-42-1) + benzoyl chloride (98-88-4) → 2-methyl-1-phenylbuta-2,3-dien-1-yl benzoate (1394905-07-7)

Guidance literature:

With triethylamine; In dichloromethane; at 0 - 20 ℃; for 5.25h;

DOI:10.1021/jo301239p

Reference yield:

2-methyl-1-phenylbuta-2,3-dien-1-yl benzoate (1394905-07-7) → C18H16O2 (1394904-86-9) + C18H16O2 (1394905-01-1)

Guidance literature:

With 2-(dicyclohexylphosphino)-2',4',6'-triisopropylbiphenyl Au bis(trifluoromethylsulfonyl)imide; In chloroform-d1; at 20 ℃; Optical yield = 74 %de; stereoselective reaction;

DOI:10.1021/jo301239p

upstream raw materials:

2-methyl-1-phenylbuta-2,3-dien-1-ol

benzoyl chloride

Downstream raw materials:

C₁₈H₁₆O₂

C₁₈H₁₆O₂

Refernces