cis,trans-Mo(CO)2(PPh₃)2(NCMe)2

Base Information

• Chemical Name: cis,trans-Mo(CO)2(PPh₃)2(NCMe)2
• CAS No.: 23526-71-8
• Molecular Formula: C₄₂H₃₆MoN₂O₂P₂
• Molecular Weight: 758.648
• Mol file: 23526-71-8.mol

Synonyms:cis,trans-Mo(CO)2(PPh₃)2(NCMe)2

Chemical Property of cis,trans-Mo(CO)2(PPh₃)2(NCMe)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis,trans-Mo(CO)2(PPh₃)2(NCMe)2

There total 2 articles about cis,trans-Mo(CO)2(PPh₃)2(NCMe)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis[2-(di-iso-propylphosphino)ethyl]amine (131890-26-1) + triphenylphosphine (603-35-0) + acetonitrile (75-05-8,26809-02-9) + molybdenum hexacarbonyl (13939-06-5,199620-15-0) → cis-[Mo(CO)2(NCMe)2(PPh3)2] (23526-71-8,64162-40-9)

Guidance literature:

acetonitrile; molybdenum hexacarbonyl; With allyl bromide; In benzene; Reflux; Inert atmosphere;

triphenylphosphine; for 1h; Reflux; Inert atmosphere;

bis[2-(di-iso-propylphosphino)ethyl]amine; In toluene; at 20 ℃; Inert atmosphere;

DOI:10.1021/acs.organomet.8b00410

Reference yield:

Mo(allyl)(carbonyl)2(acetonitrile)2(bromide) + triphenylphosphine (603-35-0) → cis,trans-Mo(CO)2(PPh3)2(NCMe)2 (23526-71-8)

Guidance literature:

In acetonitrile; suspended in MeCN; heated under reflux for 15 min;

DOI:10.1021/om991019h

Reference yield: 93.0%

cis-[Mo(CO)2(NCMe)2(PPh3)2] (23526-71-8,64162-40-9) + i-propyl isocyanide (598-45-8) → Mo(P(C6H5)3)2(CO)2(CNCH(CH3)2)2 (105015-67-6,24819-23-6)

Guidance literature:

In dichloromethane; dry N2 atmosphere; addn. of isocyanide to suspn. of Mo-compd. at room temp.; stirring for 0.5 h; concn.; pptn. on addn. of Et2O; recrystn. (CH2Cl2/EtOH); elem. anal.;

upstream raw materials:

bis[2-(di-iso-propylphosphino)ethyl]amine

triphenylphosphine

acetonitrile

molybdenum hexacarbonyl

Downstream raw materials:

cis-dicarbonyl-(2-diphenylphosphinomethylpyridine)-trans-bis(triphenylphosphine) molybdenum

dicarbonyl(N,N'-diisopropyldithiooxamide)bis(triphenylphosphine)molybdenum

dicarbonyl(dithiooxalic acid piperidide)bis(triphenylphosphine)molybdenum

Mo(P(C₆H₅)3)2(CO)2(CNCH(CH₃)2)2