POTASSIUM 3-HYDROXYPHENYLTRIFLUOROBORATE

Base Information

• Chemical Name: POTASSIUM 3-HYDROXYPHENYLTRIFLUOROBORATE
• CAS No.: 871231-45-7
• Molecular Formula: C6H5 B F3 O . K
• Molecular Weight: 200.01
• Hs Code.: 2840209090
• Mol file: 871231-45-7.mol

Synonyms:Potassium 3-hydroxyphenyltrifluoroborate;

Chemical Property of POTASSIUM 3-HYDROXYPHENYLTRIFLUOROBORATE

Chemical Property:

• Melting Point: 170-190°C(lit.)
• PSA: 20.23000
• LogP: 1.44660
• Storage Temp.: Inert atmosphere,Room Temperature

Purity/Quality:

97% ^*data from raw suppliers

Potassium 3-hydroxyphenyltrifluoroborate ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of POTASSIUM 3-HYDROXYPHENYLTRIFLUOROBORATE

There total 5 articles about POTASSIUM 3-HYDROXYPHENYLTRIFLUOROBORATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

3-Iodophenol (626-02-8) → potassium (3-hydroxyphenyl)trifluoroborate (871231-45-7)

Guidance literature:

3-Iodophenol; With tert.-butyl lithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h; Inert atmosphere;

With Triisopropyl borate; In tetrahydrofuran; hexane; at -78 - -30 ℃;

With potassium hydrogen difluoride; In tetrahydrofuran; hexane; at -30 - 20 ℃;

DOI:10.1021/ol800083j

Reference yield: 28.0%

3-Bromophenol (591-20-8) → potassium (3-hydroxyphenyl)trifluoroborate (871231-45-7)

Guidance literature:

3-Bromophenol; With tert.-butyl lithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h; Inert atmosphere;

With Triisopropyl borate; In tetrahydrofuran; hexane; at -78 - -30 ℃;

With potassium hydrogen difluoride; In tetrahydrofuran; hexane; at -30 - 20 ℃;

DOI:10.1021/ol800083j

Reference yield:

3-hydroxyphenylboronic acid (87199-18-6) → potassium (3-hydroxyphenyl)trifluoroborate (871231-45-7)

Guidance literature:

With potassium hydrogenfluoride; In methanol; water; at 0 - 20 ℃; for 0.5h; Inert atmosphere;

DOI:10.1021/ja303181m

upstream raw materials:

3-Bromophenol

3-Iodophenol

C₈H₁₁BO₃

3-monochlorophenol

Downstream raw materials:

1-benzyl-5-(3-hydroxyphenyl)-2,3-dihydropyridin-4(1H)-one

methyl 8-(benzyloxy)-5-(3-hydroxyphenyl)-2-methylquinoline-7-carboxylate

C₁₂H₁₂O₂

1-benzoyl-5-(3-hydroxyphenyl)-(2S)-isopropyl-2,3-dihydro-4(1H)-pyrimidin-4-one