2-(Benzyloxy)-3-chloro-1-methoxy-4-[(E)-2-nitroethenyl]benzene

Base Information

Chemical Name:2-(Benzyloxy)-3-chloro-1-methoxy-4-[(E)-2-nitroethenyl]benzene
CAS No.:871126-35-1
Molecular Formula:C₁₆H₁₄ClNO₄
Molecular Weight:319.744
Hs Code.:2909309090
European Community (EC) Number:621-587-5
DSSTox Substance ID:DTXSID60584558
Wikidata:Q76511207
Mol file:871126-35-1.mol

Synonyms:871126-35-1;2-(Benzyloxy)-3-chloro-1-methoxy-4-[(E)-2-nitroethenyl]benzene;TRANS-2-CHLORO-3-BENZYLOXY-4-METHOXY-BE;DTXSID60584558;(E)-2-(Benzyloxy)-3-chloro-1-methoxy-4-(2-nitrovinyl)benzene;3-chloro-1-methoxy-4-[(E)-2-nitroethenyl]-2-phenylmethoxybenzene

Suppliers and Price of 2-(Benzyloxy)-3-chloro-1-methoxy-4-[(E)-2-nitroethenyl]benzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
TRANS-3-BENZYLOXY-2-CHLORO-4-METHOXY-BETA-NITROSTYRENE Aldrich
1g
$ 144.00

Total 2 raw suppliers

Chemical Property of 2-(Benzyloxy)-3-chloro-1-methoxy-4-[(E)-2-nitroethenyl]benzene

Chemical Property:

Melting Point:96-100 °C(lit.)
PSA：64.28000
LogP:4.69820
XLogP3:4.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:5
Exact Mass:319.0611356
Heavy Atom Count:22
Complexity:379

Purity/Quality:

97% ^*data from raw suppliers

TRANS-3-BENZYLOXY-2-CHLORO-4-METHOXY-BETA-NITROSTYRENE Aldrich ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xi,N
Statements: 41-50/53
Safety Statements: 26-36/37/39-60-61

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC1=C(C(=C(C=C1)C=C[N+](=O)[O-])Cl)OCC2=CC=CC=C2
Isomeric SMILES:COC1=C(C(=C(C=C1)/C=C/[N+](=O)[O-])Cl)OCC2=CC=CC=C2

Technology Process of 2-(Benzyloxy)-3-chloro-1-methoxy-4-[(E)-2-nitroethenyl]benzene

There total 4 articles about 2-(Benzyloxy)-3-chloro-1-methoxy-4-[(E)-2-nitroethenyl]benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 75-52-5
nitromethane

: 53713-77-2
3-benzyloxy-2-chloro-4-methoxy-benzaldehyde

: 871126-35-1
2-benzyloxy-3-chloro-1-methoxy-4-[(E)-2-nitrovinyl]benzene

Guidance literature:: With ammonium acetate; In acetic acid; for 4h; Reflux;

Reference yield:

: 53713-77-2
3-benzyloxy-2-chloro-4-methoxy-benzaldehyde

: 871126-35-1
2-benzyloxy-3-chloro-1-methoxy-4-[(E)-2-nitrovinyl]benzene

Guidance literature:: With ammonium acetate;

Reference yield:

: 37687-57-3
2-chloro-3-hydroxy-4-methoxybenzaldehyde

: 871126-35-1
2-benzyloxy-3-chloro-1-methoxy-4-[(E)-2-nitrovinyl]benzene

Guidance literature:: Multi-step reaction with 2 steps

1: potassium carbonate

2: ammonium acetate

With ammonium acetate; potassium carbonate;