2,4-Difluoro-3-formylphenylboronic acid

Base Information

Chemical Name:2,4-Difluoro-3-formylphenylboronic acid
CAS No.:870718-06-2
Molecular Formula:C7H5 B F2 O3
Molecular Weight:185.923
Hs Code.:2931900090
European Community (EC) Number:635-930-1
DSSTox Substance ID:DTXSID70391098
Nikkaji Number:J3.224.005D
Wikidata:Q82188331
Mol file:870718-06-2.mol

Synonyms:2,4-Difluoro-3-formylphenylboronic acid;870718-06-2;(2,4-difluoro-3-formylphenyl)boronic acid;(2,4-Difluoro-3-formylphenyl)boronicacid;2,4-DIFLUORO-3-FORMYLPHENYL-BORONIC ACID;SCHEMBL1786706;DTXSID70391098;PVAWONNALJEQJH-UHFFFAOYSA-N;MFCD04974116;AKOS015854362;AB21497;AM90143;2,4-difluoro-3-formyl-phenylboronic acid;BP-11429;BS-17756;CS-0157872;B-(2,4-Difluoro-3-formylphenyl)boronic acid;D70601;EN300-7382450;J-519631

Suppliers and Price of 2,4-Difluoro-3-formylphenylboronic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
2,4-Difluoro-3-formylphenylboronic acid
100mg
$ 45.00

Sigma-Aldrich
2,4-Difluoro-3-formylphenylboronic acid
1g
$ 55.80

Sigma-Aldrich
2,4-Difluoro-3-formylphenylboronic acid
10g
$ 273.00

Crysdot
2,4-Difluoro-3-formylphenylboronic acid 95+%
100g
$ 701.00

Chemenu
2,4-Difluoro-3-formylphenylboronic acid 95%
5g
$ 98.00

Chemenu
2,4-Difluoro-3-formylphenylboronic acid 95%
25g
$ 349.00

AOBChem
2,4-Difluoro-3-formylphenylboronic acid 97%
1g
$ 59.00

AOBChem
2,4-Difluoro-3-formylphenylboronic acid 97%
25g
$ 298.00

American Custom Chemicals Corporation
2,4-DIFLUORO-3-FORMYLPHENYLBORONIC ACID 95.00%
1G
$ 179.55

Alichem
2,4-Difluoro-3-formylphenylboronic acid
100g
$ 708.00

Total 27 raw suppliers

Chemical Property of 2,4-Difluoro-3-formylphenylboronic acid

Chemical Property:

Vapor Pressure:5.79E-05mmHg at 25°C
Melting Point:206-210 °C(lit.)
Refractive Index:1.503
Boiling Point:332.5°C at 760 mmHg
PKA:7.72±0.58(Predicted)
Flash Point:154.9°C
PSA：57.53000
Density:1.42g/cm³
LogP:-0.54290
Storage Temp.:under inert gas (nitrogen or Argon) at 2-8°C
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:2
Exact Mass:186.0299805
Heavy Atom Count:13
Complexity:191

Purity/Quality:

97% ^*data from raw suppliers

2,4-Difluoro-3-formylphenylboronic acid ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xn
Statements: 22
Safety Statements: 36

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B(C1=C(C(=C(C=C1)F)C=O)F)(O)O

Technology Process of 2,4-Difluoro-3-formylphenylboronic acid

There total 1 articles about 2,4-Difluoro-3-formylphenylboronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 6-butyl-2-(2',4'-difluorophenyl)-(N-B)-1,3,6,2-dioxazaborocane

: 68-12-2,33513-42-7
N,N-dimethyl-formamide

: 870718-06-2
(2,4-difluoro-3-formylphenyl)boronic acid

Guidance literature:: 6-butyl-2-(2',4'-difluorophenyl)-(N-B)-1,3,6,2-dioxazaborocane; With lithium diisopropyl amide; In tetrahydrofuran; at -75 ℃; for 0.5h;

N,N-dimethyl-formamide; In tetrahydrofuran; at -75 ℃; for 0.5h;

With sulfuric acid; water; In tetrahydrofuran;
DOI:10.1002/ejoc.200900526

Reference yield: 86.0%

: 8-(methylthio)-4,4,difluoro-4-bora-3a,4a-diaza-s-indacene

: 870718-06-2
(2,4-difluoro-3-formylphenyl)boronic acid

: C₁₆H₉BF₄N₂O

Guidance literature:: With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; copper(I) thiophene-2-carboxylate; trifuran-2-yl-phosphane; In tetrahydrofuran; at 55 ℃; for 1h;
DOI:10.1002/ejoc.202001267

Reference yield: 81.0%

: 870718-06-2
(2,4-difluoro-3-formylphenyl)boronic acid

: 1278250-11-5
5-bromo-2-(4-chlorophenyl)pyrazolo[1,5-a]pyridine

: 1278652-53-1
3-[2-(4-chlorophenyl)pyrazolo[1,5-a]pyridin-5-yl]-2,6-difluorobenzaldehyde

Guidance literature:: With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; caesium carbonate; In tetrahydrofuran; water; at 60 ℃; for 2h; Inert atmosphere;