methyl 6-methyl-3-(3-methyl-but-2-enyl)-2,4-bis-(2-trimethylsilanyl-ethoxymethoxy)benzoate

Base Information

Chemical Name:methyl 6-methyl-3-(3-methyl-but-2-enyl)-2,4-bis-(2-trimethylsilanyl-ethoxymethoxy)benzoate
CAS No.:288097-94-9
Molecular Formula:C₂₆H₄₆O₆Si₂
Molecular Weight:510.819
Hs Code.:

Synonyms:methyl 6-methyl-3-(3-methyl-but-2-enyl)-2,4-bis-(2-trimethylsilanyl-ethoxymethoxy)benzoate

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Chemical Property of methyl 6-methyl-3-(3-methyl-but-2-enyl)-2,4-bis-(2-trimethylsilanyl-ethoxymethoxy)benzoate

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Technology Process of methyl 6-methyl-3-(3-methyl-but-2-enyl)-2,4-bis-(2-trimethylsilanyl-ethoxymethoxy)benzoate

There total 3 articles about methyl 6-methyl-3-(3-methyl-but-2-enyl)-2,4-bis-(2-trimethylsilanyl-ethoxymethoxy)benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 76513-69-4
(2-trimethylethylsilylethoxy)methyl chloride

: 118040-61-2
methyl 2,4-dihydroxy-6-methyl-3-(3-methyl-but-2-enyl)-benzoate

: 288097-94-9
methyl 6-methyl-3-(3-methyl-but-2-enyl)-2,4-bis-(2-trimethylsilanyl-ethoxymethoxy)benzoate

Guidance literature:: methyl 2,4-dihydroxy-6-methyl-3-(3-methyl-but-2-enyl)-benzoate; With 18-crown-6 ether; potassium hydride; In tetrahydrofuran; at 0 ℃; for 0.0833333h;

(2-trimethylethylsilylethoxy)methyl chloride; In tetrahydrofuran; at 20 ℃; for 5h; Further stages.;
DOI:10.1021/ol0061236

Reference yield:

: 3187-58-4
methyl orsellinate

: 288097-94-9
methyl 6-methyl-3-(3-methyl-but-2-enyl)-2,4-bis-(2-trimethylsilanyl-ethoxymethoxy)benzoate

Guidance literature:: Multi-step reaction with 2 steps

1.1: NaH / toluene / 4 h / 50 °C

1.2: 73 percent Turnov_. / toluene / 15 h / 35 °C

2.1: KH; 18-crown-6 / tetrahydrofuran / 0.08 h / 0 °C

2.2: 84 percent / tetrahydrofuran / 5 h / 20 °C

With 18-crown-6 ether; potassium hydride; sodium hydride; In tetrahydrofuran; toluene; 1.1: Deprotonation / 1.2: Alkylation / 2.1: Deprotonation / 2.2: Substitution;
DOI:10.1021/ol0061236

Reference yield:

: 870-63-3
prenyl bromide

: 288097-94-9
methyl 6-methyl-3-(3-methyl-but-2-enyl)-2,4-bis-(2-trimethylsilanyl-ethoxymethoxy)benzoate

Guidance literature:: Multi-step reaction with 2 steps

1.1: NaH / toluene / 4 h / 50 °C

1.2: 73 percent Turnov_. / toluene / 15 h / 35 °C

2.1: KH; 18-crown-6 / tetrahydrofuran / 0.08 h / 0 °C

2.2: 84 percent / tetrahydrofuran / 5 h / 20 °C

With 18-crown-6 ether; potassium hydride; sodium hydride; In tetrahydrofuran; toluene; 1.1: Deprotonation / 1.2: Alkylation / 2.1: Deprotonation / 2.2: Substitution;
DOI:10.1021/ol0061236