(1S,2R,4R)-4-methyl-1-(5-methyl-1-methylene-4-hexenyl)-2-(triethylsilyloxy)cyclohexane

Base Information

Chemical Name:(1S,2R,4R)-4-methyl-1-(5-methyl-1-methylene-4-hexenyl)-2-(triethylsilyloxy)cyclohexane
CAS No.:220314-69-2
Molecular Formula:C₂₁H₄₀OSi
Molecular Weight:336.633
Hs Code.:

Synonyms:(1S,2R,4R)-4-methyl-1-(5-methyl-1-methylene-4-hexenyl)-2-(triethylsilyloxy)cyclohexane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1S,2R,4R)-4-methyl-1-(5-methyl-1-methylene-4-hexenyl)-2-(triethylsilyloxy)cyclohexane

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Technology Process of (1S,2R,4R)-4-methyl-1-(5-methyl-1-methylene-4-hexenyl)-2-(triethylsilyloxy)cyclohexane

There total 3 articles about (1S,2R,4R)-4-methyl-1-(5-methyl-1-methylene-4-hexenyl)-2-(triethylsilyloxy)cyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 994-30-9
triethylsilyl chloride

: 220314-67-0
(1R,2S,5R)-5-methyl-2-(5-methyl-1-methylene-4-hexenyl)cyclohexanol

: 220314-69-2
(1S,2R,4R)-4-methyl-1-(5-methyl-1-methylene-4-hexenyl)-2-(triethylsilyloxy)cyclohexane

Guidance literature:: With pyridine; at 50 ℃; for 2h;
DOI:10.1002/(SICI)1099-0690(199902)1999:2<459::AID-EJOC459>3.0.CO;2-F

Reference yield:

: 7786-67-6,18674-65-2,20549-46-6,21290-09-5,29141-10-4,50373-36-9,59905-53-2,59905-54-3,96612-21-4,104870-56-6,121468-66-4,122517-60-6,122517-61-7,144541-38-8,89-79-2
isopulegol

: 220314-69-2
(1S,2R,4R)-4-methyl-1-(5-methyl-1-methylene-4-hexenyl)-2-(triethylsilyloxy)cyclohexane

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) BuLi, K-OtBu / 1.) hexane, 0 deg C, 2 h, 2.) hexane, 25 deg C, 15 min

2: 86 percent / pyridine / 2 h / 50 °C

With pyridine; n-butyllithium; potassium tert-butylate;
DOI:10.1002/(SICI)1099-0690(199902)1999:2<459::AID-EJOC459>3.0.CO;2-F

Reference yield:

: 870-63-3
prenyl bromide

: 220314-69-2
(1S,2R,4R)-4-methyl-1-(5-methyl-1-methylene-4-hexenyl)-2-(triethylsilyloxy)cyclohexane

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) BuLi, K-OtBu / 1.) hexane, 0 deg C, 2 h, 2.) hexane, 25 deg C, 15 min

2: 86 percent / pyridine / 2 h / 50 °C

With pyridine; n-butyllithium; potassium tert-butylate;
DOI:10.1002/(SICI)1099-0690(199902)1999:2<459::AID-EJOC459>3.0.CO;2-F