(5-hexyl-10,20-diphenylporphyrinato)zinc(II)

Base Information

• Chemical Name: (5-hexyl-10,20-diphenylporphyrinato)zinc(II)
• CAS No.: 1314641-98-9
• Molecular Formula: C₃₈H₃₂N₄Zn
• Molecular Weight: 610.089
• Mol file: 1314641-98-9.mol

Synonyms:(5-hexyl-10,20-diphenylporphyrinato)zinc(II)

Chemical Property of (5-hexyl-10,20-diphenylporphyrinato)zinc(II)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of (5-hexyl-10,20-diphenylporphyrinato)zinc(II)

There total 1 articles about (5-hexyl-10,20-diphenylporphyrinato)zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

5-hexyl-10,20-diphenylporphyrine + zinc(II) oxide → (5-hexyl-10,20-diphenylporphyrinato)zinc(II) (1314641-98-9)

Guidance literature:

With trifluoroacetic acid; In dichloromethane; porphyrin in CH2Cl2 treated with ZnO; 4 drops of CF3COOH added; filtered through short silica column; washed with water; dried with Na2SO4; solvent removed in vacuo; purified by column chromy.; recrystd. fromCH2Cl2/MeOH;

DOI:10.1515/znb-2011-0601

Reference yield: 82.0%

(5-hexyl-10,20-diphenylporphyrinato)zinc(II) (1314641-98-9) → bis[(5-hexyl-10,20-diphenylporphyrin-13,15,17-triylato)zinc(II)] (1314641-99-0)

Guidance literature:

With DDQ; Sc(OTf)3; In tetrahydrofuran; toluene; Zn porphyrinate in toluene heated to 50°C; then DDQ and Sc(OTf)3 in dry toluene added, stirred for 3 h; THF added; stirred for 60 min; react. mixt. filtered through silica gel; solvent removed under reduced pressure; residue purified by column chromy. (CH2Cl2/CH3OH = 50:1);

DOI:10.1515/znb-2011-0601

Reference yield: 42.0%

(5-hexyl-10,20-diphenylporphyrinato)zinc(II) (1314641-98-9) → bis[(5-hexyl-10,20-diphenylporphyrin-15-ylato)zinc(II)] (1314641-97-8) + bis[(5-hexyl-10,20-diphenylporphyrin-13,15,17-triylato)zinc(II)] (1314641-99-0)

Guidance literature:

With 2,3-dicyano-5,6-dichloro-p-benzoquinone; scandium tris(trifluoromethanesulfonate); In toluene; at 50 ℃; for 3h;

DOI:10.1002/ejoc.201201622

Downstream raw materials:

bis[(5-hexyl-10,20-diphenylporphyrin-15-ylato)zinc(II)]

bis[(5-hexyl-10,20-diphenylporphyrin-13,15,17-triylato)zinc(II)]