Technology Process of C50H50O10
There total 6 articles about C50H50O10 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
sodium chlorite; aminosulfonic acid;
In
water; acetone;
at 0 ℃;
for 0.333333h;
DOI:10.1021/ol500725e
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: n-butyllithium; isopropylmagnesium chloride / tetrahydrofuran; cyclohexane / 0.75 h / -78 - -20 °C
1.2: 0.5 h / -20 °C
2.1: sodium iodide; aluminum (III) chloride / acetonitrile / 1 h / 80 °C / Inert atmosphere
3.1: sodium hexamethyldisilazane / N,N-dimethyl-formamide; tetrahydrofuran / -78 - 20 °C / Inert atmosphere
3.2: 18 h / 20 °C / Inert atmosphere
4.1: sodium chlorite; aminosulfonic acid / acetone; water / 0.33 h / 0 °C
With
aluminum (III) chloride; sodium chlorite; n-butyllithium; aminosulfonic acid; isopropylmagnesium chloride; sodium hexamethyldisilazane; sodium iodide;
In
tetrahydrofuran; cyclohexane; water; N,N-dimethyl-formamide; acetone; acetonitrile;
DOI:10.1021/ol500725e
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: boron trifluoride diethyl etherate / dichloromethane / 0.5 h / 0 °C
2.1: n-butyllithium; N,N,N,N,-tetramethylethylenediamine
3.1: sodium iodide; aluminum (III) chloride / acetonitrile / 1 h / 80 °C / Inert atmosphere
4.1: sodium hexamethyldisilazane / N,N-dimethyl-formamide; tetrahydrofuran / -78 - 20 °C / Inert atmosphere
4.2: 18 h / 20 °C / Inert atmosphere
5.1: sodium chlorite; aminosulfonic acid / acetone; water / 0.33 h / 0 °C
With
aluminum (III) chloride; sodium chlorite; n-butyllithium; N,N,N,N,-tetramethylethylenediamine; boron trifluoride diethyl etherate; aminosulfonic acid; sodium hexamethyldisilazane; sodium iodide;
In
tetrahydrofuran; dichloromethane; water; N,N-dimethyl-formamide; acetone; acetonitrile;
1.1: |Friedel-Crafts Alkylation;
DOI:10.1021/ol500725e