(2R,3R,4R,5S,6R)-2-Allyloxy-3,4,5-tris-benzyloxy-6-(4-methoxy-benzyloxy)-cyclohexanone

Base Information

Chemical Name:(2R,3R,4R,5S,6R)-2-Allyloxy-3,4,5-tris-benzyloxy-6-(4-methoxy-benzyloxy)-cyclohexanone
CAS No.:135131-60-1
Molecular Formula:C₃₈H₄₀O₇
Molecular Weight:608.731
Hs Code.:

Synonyms:(2R,3R,4R,5S,6R)-2-Allyloxy-3,4,5-tris-benzyloxy-6-(4-methoxy-benzyloxy)-cyclohexanone

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Chemical Property of (2R,3R,4R,5S,6R)-2-Allyloxy-3,4,5-tris-benzyloxy-6-(4-methoxy-benzyloxy)-cyclohexanone

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Technology Process of (2R,3R,4R,5S,6R)-2-Allyloxy-3,4,5-tris-benzyloxy-6-(4-methoxy-benzyloxy)-cyclohexanone

There total 11 articles about (2R,3R,4R,5S,6R)-2-Allyloxy-3,4,5-tris-benzyloxy-6-(4-methoxy-benzyloxy)-cyclohexanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 135131-58-7
1-O-Allyl-2,3,4-tri-O-benzyl-5-O-(p-methoxybenzyl)-D-chiro-inositol

: 135131-60-1
(2R,3R,4R,5S,6R)-2-Allyloxy-3,4,5-tris-benzyloxy-6-(4-methoxy-benzyloxy)-cyclohexanone

Guidance literature:: With pyridinium chlorochromate; In dichloromethane; for 13h; Ambient temperature;
DOI:10.1021/jo00090a035

Reference yield:

: 133218-74-3
4,5,6-tri-O-benzyl-1,2-anhydro-myo-inositol

: 135131-60-1
(2R,3R,4R,5S,6R)-2-Allyloxy-3,4,5-tris-benzyloxy-6-(4-methoxy-benzyloxy)-cyclohexanone

Guidance literature:: Multi-step reaction with 3 steps

1: 75 percent / BF₃*Et₂O / CH₂Cl₂ / 3.5 h / Ambient temperature

2: 85 percent / Bu₂SnO, 3 Angstroem molecular sieves, Bu₄NBr / acetonitrile / 5 h / 80 °C

3: 89 percent / PCC / CH₂Cl₂ / 13 h / Ambient temperature

With 3 A molecular sieve; boron trifluoride diethyl etherate; tetrabutylammomium bromide; di(n-butyl)tin oxide; pyridinium chlorochromate; In dichloromethane; acetonitrile;
DOI:10.1021/jo00090a035

Reference yield:

: 135267-00-4,1214020-75-3
1-O-Allyl-2,3,4-tri-O-benzyl-D-chiro-inositol

: 135131-60-1
(2R,3R,4R,5S,6R)-2-Allyloxy-3,4,5-tris-benzyloxy-6-(4-methoxy-benzyloxy)-cyclohexanone

Guidance literature:: Multi-step reaction with 2 steps

1: 85 percent / Bu₂SnO, 3 Angstroem molecular sieves, Bu₄NBr / acetonitrile / 5 h / 80 °C

2: 89 percent / PCC / CH₂Cl₂ / 13 h / Ambient temperature

With 3 A molecular sieve; tetrabutylammomium bromide; di(n-butyl)tin oxide; pyridinium chlorochromate; In dichloromethane; acetonitrile;
DOI:10.1021/jo00090a035