133218-74-3

Basic information

• Product Name: 4,5,6-tri-O-benzyl-1,2-anhydro-myo-inositol
• Synonyms: 4,5,6-tri-O-benzyl-1,2-anhydro-myo-inositol
• CAS NO: 133218-74-3
• Molecular Weight: 432.516
• Mol File: 133218-74-3.mol

Chemical Properties

• CAS DataBase Reference: 4,5,6-tri-O-benzyl-1,2-anhydro-myo-inositol(CAS DataBase Reference)
• NIST Chemistry Reference: 4,5,6-tri-O-benzyl-1,2-anhydro-myo-inositol(133218-74-3)
• EPA Substance Registry System: 4,5,6-tri-O-benzyl-1,2-anhydro-myo-inositol(133218-74-3)

Safety Data

• Hazardous Substances Data: 133218-74-3(Hazardous Substances Data)

Upstream product

• 18311-26-7 methyl 6-O-trityl-α-D-glucopyranoside 
• 97-30-3 methyl-alpha-D-glucopyranoside 
• 53008-65-4 methyl 2,3,4-tri-O-benzyl-D-glucopyranoside 
• 2595-06-4 methyl 2,3,4-tri-O-benzyl-6-O-trityl-α-D-glucopyranoside 
• 606930-14-7 (2S,3R,4S)-2,3,4-tris-benzyloxy-5-hydroxycyclohexan-1-one 
• 85716-44-5 methyl 2,3,4-tri-O-benzyl-α-d-xylo-hex-5-enopyranoside 
• 85798-11-4 (4S,5R,6S)-4,5,6-tris-benzyloxycyclohex-2-en-1-one 
• 102997-58-0 (1R,2R,3S)-tris(phenylmethoxy)-6S-hydroxy-cyclohex-4-ene 
• 85716-43-4 methyl 6-deoxy-6-iodo-2,3,4-tri-O-benzyl-α-D-glucopyranoside 

Downstream Products

• 135267-00-4 1-O-Allyl-2,3,4-tri-O-benzyl-D-chiro-inositol 
• 126661-83-4 cyclophellitol 
• 139402-99-6 (1S,2S,3R,4S,5R,6R)-2,3,4,5-tetrahydroxy-6-(hydroxymethyl)cyclohexyl methanesulfonate 
• 906748-02-5 (1S,2R,3S,4S,5R,6S)-2,3,4,5-tetrakis(benzyloxy)-6-[(benzyloxy)methyl]cyclohexanol 
• 214411-20-8 (1S,2S,3R,4S,5R,6R)-2,3,4,5-tetrakis(benzyloxy)-6-[(benzyloxy)methyl]cyclohexyl methanesulfonate 
• 214203-47-1 (1R,2S,3R,4R,5S,6R)-2,3,4-tris(benzyloxy)-6-(hydroxymethyl)-5-[(4-methoxybenzyl)oxy]cyclohexanol 
• 214203-48-2 1-methoxy-4-[[(1S,2R,3R,4S,5R,6S)-2,3,4,5-tetrakis(benzyloxy)-6-[(benzyloxy)methyl]-1-cyclohexyl]oxymethyl]benzene 
• 158215-61-3 2-O-Allyl-3,4,5-tri-O-benzyl-1-O-(dibenzylphosphono)-6-(6-O-acetyl-2-azido-3,4-di-O-benzyl-2-deoxy-α-D-glucopyranosyl)-D-myo-inositol 
• 1053733-28-0 Phosphoric acid (1R,2R,3R,4R,5S,6R)-2-allyloxy-6-((2R,3R,4R,5S,6R)-3-azido-4,5-bis-benzyloxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-3,4,5-tris-benzyloxy-cyclohexyl ester dibenzyl ester 
• 158215-62-4 3,4,5-Tri-O-benzyl-1-O-(dibenzylphosphono)-6-(2-azido-2-deoxy-3,4-dibenzyl-α-D-glucopyranosyl)-D-myo-inositol 
• 158215-56-6 1-(6-O-Acetyl-2-azido-2-deoxy-3,4-dibenzyl-α-D-glucopyranosyl)-6-O-allyl-2,3,4,5-tetra-O-benzyl-D-chiro-inositol 
• 158215-57-7 1-(6-O-Acetyl-2-azido-2-deoxy-3,4-dibenzyl-α-D-glucopyranosyl)-2,3,4,5-tetra-O-benzyl-D-chiro-inositol 
• 158215-59-9 2-O-Allyl-3,4,5-tri-O-benzyl-1-O-(dibenzylphosphono)-6-O-(p-methoxybenzyl)-D-myo-inositol 
• 158215-60-2 2-O-Allyl-3,4,5-tri-O-benzyl-1-O-(dibenzylphosphono)-D-myo-inositol 

Relevant articles and documents

Synthesis of cyclophellitol utilizing a palladium chloride mediated-ferrier-II rearrangement

Cyclophellitol and its C3-epimer have been synthesized from 5-enoglucopyranoside and 5-enomannopyranoside, respectively. The carbocyclic skeleton was constructed through a Ferrier-II reaction meditated by PdCl 2.

An efficient synthesis of cyclophellitol utilizing unusual regioselectivity of oxirane ring opening with Mes2BCH2Li

Cyclophellitol has been synthesized from 5,6-enoglucoside efficiently. The carbacyclic skeleton was constructed through a Ferrier reaction mediated by PdCl2. The regioselectivity on the oxirane ring opening with Mes2BCH2Li

An effective strategy for the synthesis of 6-O-(2-amino-2-deoxy-α-D-glucopyranosyl)-D-chiro- and -D-myo-inositol 1-phosphate related to putative insulin mimetics

Two glycosylinositol phosphates related to putative insulin mimetics, 6-O-(2-amino-2-deoxy-α-D-glucopyranosyl)-D-chiro-inositol 1-phosphate (1) and 6-O-(2-amino-2-deoxy-α-D-glucopyranosyl)-D-myo-inositol 1-phosphate (2), have been synthesized from selectively protected and enantiomerically pure D-chiro- and myo-inositol derivatives. The D-chiro-inositol unit was prepared in a multigram scale from D-glucose using the Ferrier's carbocyclization route, and it was transformed into the corresponding myo epimer by an oxidation-reduction sequence. The trichloroacetimidate method was applied efficiently for the key glycosylation of the inositol derivatives.