S-dodecyl (2R,3S)-5-(tert-butyldiphenylsilyloxy)-2-methyl-3-(triethylsilyloxy)pentanethioate

Base Information

Chemical Name:S-dodecyl (2R,3S)-5-(tert-butyldiphenylsilyloxy)-2-methyl-3-(triethylsilyloxy)pentanethioate
CAS No.:1189804-53-2
Molecular Formula:C₄₀H₆₈O₃SSi₂
Molecular Weight:685.215
Hs Code.:

Synonyms:S-dodecyl (2R,3S)-5-(tert-butyldiphenylsilyloxy)-2-methyl-3-(triethylsilyloxy)pentanethioate

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Chemical Property of S-dodecyl (2R,3S)-5-(tert-butyldiphenylsilyloxy)-2-methyl-3-(triethylsilyloxy)pentanethioate

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Technology Process of S-dodecyl (2R,3S)-5-(tert-butyldiphenylsilyloxy)-2-methyl-3-(triethylsilyloxy)pentanethioate

There total 1 articles about S-dodecyl (2R,3S)-5-(tert-butyldiphenylsilyloxy)-2-methyl-3-(triethylsilyloxy)pentanethioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 1189804-50-9
(R)-4-benzyl-3-((2R,3S)-5-(tert-butyldiphenylsilyloxy)-2-methyl-3-(triethylsilyloxy)pentanoyl)oxazolidin-2-one

: 112-55-0
1-dodecylthiol

: 1189804-53-2
S-dodecyl (2R,3S)-5-(tert-butyldiphenylsilyloxy)-2-methyl-3-(triethylsilyloxy)pentanethioate

Guidance literature:: 1-dodecylthiol; With n-butyllithium; In tetrahydrofuran; hexane; at 0 ℃; for 0.5h;

(R)-4-benzyl-3-((2R,3S)-5-(tert-butyldiphenylsilyloxy)-2-methyl-3-(triethylsilyloxy)pentanoyl)oxazolidin-2-one; In tetrahydrofuran; hexane; at -78 - 0 ℃;
DOI:10.1016/j.tet.2009.07.070

Reference yield: 55.0%

: 1189804-36-1
((3S,4R,5R)-5-allyloxy-1-benzyloxy-3-methoxy-6,6-dimethyloct-7-yn-4-yloxy)triethylsilane

: 1189804-53-2
S-dodecyl (2R,3S)-5-(tert-butyldiphenylsilyloxy)-2-methyl-3-(triethylsilyloxy)pentanethioate

: C₅₂H₈₆O₈Si₂

: 1189804-55-4
(7S,8R)-13-(allyloxy)-14-(3-(benzyloxy)-1-methoxypropyl)-16,16-diethyl-2,2,8,12,12-pentamethyl-3,3-diphenyl-7-(triethylsilyloxy)-4,15-dioxa-3,16-disilaoctadec-10-yn-9-one

Guidance literature:: With copper(l) iodide; palladium bis[bis(diphenylphosphino)ferrocene] dichloride; trifuran-2-yl-phosphane; triethylamine; In N,N-dimethyl-formamide; at 50 ℃; for 3h;
DOI:10.1016/j.tet.2009.07.070

Reference yield: 50.0%

: 1189804-53-2
S-dodecyl (2R,3S)-5-(tert-butyldiphenylsilyloxy)-2-methyl-3-(triethylsilyloxy)pentanethioate

: 1253891-03-0
(5R,6R)-5-((S)-2-((4S,5S,6R)-6-((R)-but-3-en-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)-1-methoxyethyl)-3,3,8,8-tetraethyl-6-(2-methylbut-3-yn-2-yl)-4,7-dioxa-3,8-disiladecane

: 1253891-02-9
(6R,7R,12R,13R)-13-((S)-2-((4S,5S,6R)-6-((R)-but-3-en-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)-1-methoxyethyl)-15,15-diethyl-2,2,7,11,11-pentamethyl-3,3-diphenyl-6,12-bis(triethylsilyloxy)-4,14-dioxa-3,15-disilaheptadec-9-yn-8-one

: C₆₆H₁₂₆O₁₀Si₄

Guidance literature:: With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; copper(l) iodide; trifuran-2-yl-phosphane; triethylamine; In N,N-dimethyl-formamide; at 50 ℃; for 3h;
DOI:10.1039/c0ob00092b