(6R,7R,12R,13R)-13-((S)-2-((4S,5S,6R)-6-((R)-but-3-en-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)-1-methoxyethyl)-15,15-diethyl-2,2,7,11,11-pentamethyl-3,3-diphenyl-6,12-bis(triethylsilyloxy)-4,14-dioxa-3,15-disilaheptadec-9-yn-8-one

Base Information

Chemical Name:(6R,7R,12R,13R)-13-((S)-2-((4S,5S,6R)-6-((R)-but-3-en-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)-1-methoxyethyl)-15,15-diethyl-2,2,7,11,11-pentamethyl-3,3-diphenyl-6,12-bis(triethylsilyloxy)-4,14-dioxa-3,15-disilaheptadec-9-yn-8-one
CAS No.:1253891-02-9
Molecular Formula:C₆₁H₁₀₆O₈Si₄
Molecular Weight:1079.85
Hs Code.:

(6R,7R,12R,13R)-13-((S)-2-((4S,5S,6R)-6-((R)-but-3-en-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)-1-methoxyethyl)-15,15-diethyl-2,2,7,11,11-pentamethyl-3,3-diphenyl-6,12-bis(triethylsilyloxy)-4,14-dioxa-3,15-disilaheptadec-9-yn-8-one

Synonyms:(6R,7R,12R,13R)-13-((S)-2-((4S,5S,6R)-6-((R)-but-3-en-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)-1-methoxyethyl)-15,15-diethyl-2,2,7,11,11-pentamethyl-3,3-diphenyl-6,12-bis(triethylsilyloxy)-4,14-dioxa-3,15-disilaheptadec-9-yn-8-one

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Chemical Property of (6R,7R,12R,13R)-13-((S)-2-((4S,5S,6R)-6-((R)-but-3-en-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)-1-methoxyethyl)-15,15-diethyl-2,2,7,11,11-pentamethyl-3,3-diphenyl-6,12-bis(triethylsilyloxy)-4,14-dioxa-3,15-disilaheptadec-9-yn-8-one

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Technology Process of (6R,7R,12R,13R)-13-((S)-2-((4S,5S,6R)-6-((R)-but-3-en-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)-1-methoxyethyl)-15,15-diethyl-2,2,7,11,11-pentamethyl-3,3-diphenyl-6,12-bis(triethylsilyloxy)-4,14-dioxa-3,15-disilaheptadec-9-yn-8-one

There total 1 articles about (6R,7R,12R,13R)-13-((S)-2-((4S,5S,6R)-6-((R)-but-3-en-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)-1-methoxyethyl)-15,15-diethyl-2,2,7,11,11-pentamethyl-3,3-diphenyl-6,12-bis(triethylsilyloxy)-4,14-dioxa-3,15-disilaheptadec-9-yn-8-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 1189804-53-2
S-dodecyl (2R,3S)-5-(tert-butyldiphenylsilyloxy)-2-methyl-3-(triethylsilyloxy)pentanethioate

: 1253891-03-0
(5R,6R)-5-((S)-2-((4S,5S,6R)-6-((R)-but-3-en-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)-1-methoxyethyl)-3,3,8,8-tetraethyl-6-(2-methylbut-3-yn-2-yl)-4,7-dioxa-3,8-disiladecane

: 1253891-02-9
(6R,7R,12R,13R)-13-((S)-2-((4S,5S,6R)-6-((R)-but-3-en-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)-1-methoxyethyl)-15,15-diethyl-2,2,7,11,11-pentamethyl-3,3-diphenyl-6,12-bis(triethylsilyloxy)-4,14-dioxa-3,15-disilaheptadec-9-yn-8-one

: C₆₆H₁₂₆O₁₀Si₄

Guidance literature:: With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; copper(l) iodide; trifuran-2-yl-phosphane; triethylamine; In N,N-dimethyl-formamide; at 50 ℃; for 3h;
DOI:10.1039/c0ob00092b

Reference yield: 33.0%

: 1253891-02-9
(6R,7R,12R,13R)-13-((S)-2-((4S,5S,6R)-6-((R)-but-3-en-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)-1-methoxyethyl)-15,15-diethyl-2,2,7,11,11-pentamethyl-3,3-diphenyl-6,12-bis(triethylsilyloxy)-4,14-dioxa-3,15-disilaheptadec-9-yn-8-one

: 1253891-10-9
(2S,3R,7S,8R)-2-((S)-2-((4S,5S,6R)-6-((R)-but-3-en-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)-1-methoxyethyl)-7-(2-(tert-butyldiphenylsilyloxy)ethyl)-3-hydroxy-4,4,8-trimethyl-1,6-dioxaspiro[4.5]decan-9-one

Guidance literature:: With toluene-4-sulfonic acid; In toluene; at 20 ℃; for 24h;
DOI:10.1039/c0ob00092b

Reference yield: 31.0%

: 1253891-02-9
(6R,7R,12R,13R)-13-((S)-2-((4S,5S,6R)-6-((R)-but-3-en-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)-1-methoxyethyl)-15,15-diethyl-2,2,7,11,11-pentamethyl-3,3-diphenyl-6,12-bis(triethylsilyloxy)-4,14-dioxa-3,15-disilaheptadec-9-yn-8-one

: 1253891-10-9
(2S,3R,7S,8R)-2-((S)-2-((4S,5S,6R)-6-((R)-but-3-en-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)-1-methoxyethyl)-7-(2-(tert-butyldiphenylsilyloxy)ethyl)-3-hydroxy-4,4,8-trimethyl-1,6-dioxaspiro[4.5]decan-9-one

: 1253891-11-0
(2R,3R,7S,8R)-2-((S)-2-((4S,5S,6R)-6-((R)-but-3-en-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)-1-methoxyethyl)-7-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-4,4,8-trimethyl-3-((triethylsilyl)oxy)-1,6-dioxaspiro[4.5]decan-9-one

Guidance literature:: (6R,7R,12R,13R)-13-((S)-2-((4S,5S,6R)-6-((R)-but-3-en-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)-1-methoxyethyl)-15,15-diethyl-2,2,7,11,11-pentamethyl-3,3-diphenyl-6,12-bis(triethylsilyloxy)-4,14-dioxa-3,15-disilaheptadec-9-yn-8-one; With [(1S)-7,7-dimethyl-2-oxobicyclo[2.2.1]hept-1-yl]methanesulfonic acid; In methanol; dichloromethane; at 20 ℃; for 1h;

With toluene-4-sulfonic acid; In water; toluene; at 20 ℃; for 4h;
DOI:10.1039/c0ob00092b