Technology Process of C39H56O4Si2
There total 4 articles about C39H56O4Si2 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Methyltriphenylphosphonium bromide;
With
sodium hexamethyldisilazane;
In
tetrahydrofuran; toluene;
at 0 ℃;
for 0.5h;
Inert atmosphere;
C38H54O5Si2;
In
tetrahydrofuran; toluene;
at -78 - 0 ℃;
Inert atmosphere;
DOI:10.1021/ja109533y
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: 10-camphorsufonic acid / methanol / 3 h / 25 °C / Inert atmosphere
2.1: tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide / dichloromethane / 0 - 25 °C / Inert atmosphere; Molecular sieve
3.1: sodium hexamethyldisilazane / tetrahydrofuran; toluene / 0.5 h / 0 °C / Inert atmosphere
3.2: -78 - 0 °C / Inert atmosphere
With
tetrapropylammonium perruthennate; 10-camphorsufonic acid; sodium hexamethyldisilazane; 4-methylmorpholine N-oxide;
In
tetrahydrofuran; methanol; dichloromethane; toluene;
3.1: Wittig reaction / 3.2: Wittig reaction;
DOI:10.1021/ja109533y
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: 2,6-dimethylpyridine / dichloromethane / 2 h / 25 °C / Inert atmosphere
2.1: 10-camphorsufonic acid / methanol / 3 h / 25 °C / Inert atmosphere
3.1: tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide / dichloromethane / 0 - 25 °C / Inert atmosphere; Molecular sieve
4.1: sodium hexamethyldisilazane / tetrahydrofuran; toluene / 0.5 h / 0 °C / Inert atmosphere
4.2: -78 - 0 °C / Inert atmosphere
With
2,6-dimethylpyridine; tetrapropylammonium perruthennate; 10-camphorsufonic acid; sodium hexamethyldisilazane; 4-methylmorpholine N-oxide;
In
tetrahydrofuran; methanol; dichloromethane; toluene;
4.1: Wittig reaction / 4.2: Wittig reaction;
DOI:10.1021/ja109533y
