3-[2-isopropyl-5-methylcyclohexyloxy-(1R,2S,5R)]-2-methyl-2E-propenal

Base Information

• Chemical Name: 3-[2-isopropyl-5-methylcyclohexyloxy-(1R,2S,5R)]-2-methyl-2E-propenal
• CAS No.: 250267-09-5
• Molecular Formula: C₁₄H₂₄O₂
• Molecular Weight: 224.343
• Mol file: 250267-09-5.mol

Synonyms:3-[2-isopropyl-5-methylcyclohexyloxy-(1R,2S,5R)]-2-methyl-2E-propenal

Chemical Property of 3-[2-isopropyl-5-methylcyclohexyloxy-(1R,2S,5R)]-2-methyl-2E-propenal

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of 3-[2-isopropyl-5-methylcyclohexyloxy-(1R,2S,5R)]-2-methyl-2E-propenal

There total 1 articles about 3-[2-isopropyl-5-methylcyclohexyloxy-(1R,2S,5R)]-2-methyl-2E-propenal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

3-ethoxy-2-methylacrolein (62055-46-3) + (-)-menthol (2216-51-5) → 3-[2-isopropyl-5-methylcyclohexyloxy-(1R,2S,5R)]-2-methyl-2E-propenal (250267-09-5)

Guidance literature:

With toluene-4-sulfonic acid; for 24h; under 23 Torr;

DOI:10.1016/S0040-4020(99)00666-3

Reference yield: 65.0%

Methylenetriphenylphosphorane (19493-09-5) + 3-[2-isopropyl-5-methylcyclohexyloxy-(1R,2S,5R)]-2-methyl-2E-propenal (250267-09-5) → 2-methyl-1E,3-butadiene, [2-isopropyl-5-methylcyclohexyl(1R,2S,5R)]ether (250267-11-9)

Guidance literature:

In tetrahydrofuran; hexane;

DOI:10.1016/S0040-4020(99)00666-3

Reference yield:

3-[2-isopropyl-5-methylcyclohexyloxy-(1R,2S,5R)]-2-methyl-2E-propenal (250267-09-5) → 1-[1-hydroperoxy-2-methylene-3-butene], [2-isopropyl-5-methylcyclohexyloxy-(1R, 2S, 5R)]

Guidance literature:

Multi-step reaction with 2 steps

1: 65 percent / tetrahydrofuran; hexane

2: tetraphenylporphyrin; ¹O₂ / CH₂Cl₂ / 0.17 h / 0 °C / Irradiation

With oxygen; 5,15,10,20-tetraphenylporphyrin; In tetrahydrofuran; hexane; dichloromethane; 1: Condensation / 2: Oxidation;

DOI:10.1016/S0040-4020(99)00666-3

upstream raw materials:

3-ethoxy-2-methylacrolein

(-)-menthol

Downstream raw materials:

2-methyl-1E,3-butadiene, [2-isopropyl-5-methylcyclohexyl(1R,2S,5R)]ether