2-((2R,4S,5R,6S)-5-(benzyloxy)-4-methoxy-2,6-dimethyloct-7-enyl)-1,4-diisopropoxy-3-methoxybenzene

Base Information

Chemical Name:2-((2R,4S,5R,6S)-5-(benzyloxy)-4-methoxy-2,6-dimethyloct-7-enyl)-1,4-diisopropoxy-3-methoxybenzene
CAS No.:1402167-28-5
Molecular Formula:C₃₁H₄₆O₅
Molecular Weight:498.703
Hs Code.:

Synonyms:2-((2R,4S,5R,6S)-5-(benzyloxy)-4-methoxy-2,6-dimethyloct-7-enyl)-1,4-diisopropoxy-3-methoxybenzene

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Chemical Property of 2-((2R,4S,5R,6S)-5-(benzyloxy)-4-methoxy-2,6-dimethyloct-7-enyl)-1,4-diisopropoxy-3-methoxybenzene

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Technology Process of 2-((2R,4S,5R,6S)-5-(benzyloxy)-4-methoxy-2,6-dimethyloct-7-enyl)-1,4-diisopropoxy-3-methoxybenzene

There total 1 articles about 2-((2R,4S,5R,6S)-5-(benzyloxy)-4-methoxy-2,6-dimethyloct-7-enyl)-1,4-diisopropoxy-3-methoxybenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 1118756-81-2
C₂₄H₄₀O₅

: 100-39-0
benzyl bromide

: 1402167-28-5
2-((2R,4S,5R,6S)-5-(benzyloxy)-4-methoxy-2,6-dimethyloct-7-enyl)-1,4-diisopropoxy-3-methoxybenzene

Guidance literature:: With potassium hydride; In tetrahydrofuran; mineral oil; at 0 - 20 ℃; for 16h;
DOI:10.1002/chem.201201600

Reference yield:

: 1402167-28-5
2-((2R,4S,5R,6S)-5-(benzyloxy)-4-methoxy-2,6-dimethyloct-7-enyl)-1,4-diisopropoxy-3-methoxybenzene

: C₃₁H₄₈O₇

Guidance literature:: With osmium(VIII) oxide; 4-methylmorpholine N-oxide; In dichloromethane; water; at 20 ℃; for 16h;
DOI:10.1002/chem.201201600

Reference yield:

: 1402167-28-5
2-((2R,4S,5R,6S)-5-(benzyloxy)-4-methoxy-2,6-dimethyloct-7-enyl)-1,4-diisopropoxy-3-methoxybenzene

: 1402167-76-3
(2E,4Z,6S,7S,8E,10S,11R,12S,14R)-11-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-15-(2',5'-diisopropoxy-6'-methoxy-3'-nitrophenyl)-6,12-dimethoxy-2,8,10,14-tetramethylpentadeca-2,4,8-trien-1-ol

Guidance literature:: Multi-step reaction with 8 steps

1: osmium(VIII) oxide; 4-methylmorpholine N-oxide / dichloromethane; water / 16 h / 20 °C

2: sodium periodate / water; acetone / 1 h / 20 °C

3: samarium diiodide / tetrahydrofuran / 1 h / -78 °C

4: Martins sulfurane / dichloromethane / 1 h / 0 °C

5: dimethylsulfide borane complex; (S)-1-methyl-3,3-diphenyl-hexahydropyrrolo[1,2-c][1,3,2]oxazaborole / tetrahydrofuran; toluene / 0.25 h / -30 °C

6: 1H-imidazole / N,N-dimethyl-formamide / 16 h

7: copper(II) nitrate / acetic anhydride / 2.25 h / 0 °C

8: pyridine; pyridine hydrogenfluoride / tetrahydrofuran / 12 h / 20 °C

With pyridine; 1H-imidazole; sodium periodate; osmium(VIII) oxide; samarium diiodide; Martins sulfurane; dimethylsulfide borane complex; copper(II) nitrate; pyridine hydrogenfluoride; 4-methylmorpholine N-oxide; (S)-1-methyl-3,3-diphenyl-hexahydropyrrolo[1,2-c][1,3,2]oxazaborole; In tetrahydrofuran; dichloromethane; water; acetic anhydride; N,N-dimethyl-formamide; acetone; toluene; 3: Reformatsky-type reaction;
DOI:10.1002/chem.201201600