monomeric N-benzylcarbamic acid

Base Information

• Chemical Name: monomeric N-benzylcarbamic acid
• CAS No.: 85600-10-8
• Molecular Formula: C₈H₉NO₂
• Molecular Weight: 151.165
• Mol file: 85600-10-8.mol

Synonyms:monomeric N-benzylcarbamic acid

Chemical Property of monomeric N-benzylcarbamic acid

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of monomeric N-benzylcarbamic acid

There total 4 articles about monomeric N-benzylcarbamic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

carbon dioxide (124-38-9,18923-20-1) + benzylamine (100-46-9) → monomeric N-benzylcarbamic acid (85600-10-8)

Guidance literature:

In acetonitrile;

DOI:10.1039/c9ta09500d

Reference yield:

N-Benzylammonium-N'-benzylcarbaminat (85600-11-9) → carbon dioxide (124-38-9,18923-20-1) + monomeric N-benzylcarbamic acid (85600-10-8) + benzylamine (100-46-9)

Guidance literature:

In tetrahydrofuran; Further byproducts given. Title compound not separated from byproducts;

DOI:10.1016/S0040-4020(01)92239-2

Reference yield:

N-Benzylammonium-N'-benzylcarbaminat (85600-11-9) → carbon dioxide (124-38-9,18923-20-1) + monomeric N-benzylcarbamic acid (85600-10-8) + benzylamine (100-46-9)

Guidance literature:

In tetrahydrofuran; Product distribution; chemical stability in solution; or 13C-labelled compound;

DOI:10.1016/S0040-4020(01)92239-2

upstream raw materials:

carbon dioxide

benzylamine

N-Benzylammonium-N'-benzylcarbaminat

benzyl isothiocyanate

Downstream raw materials:

hydroxymethyl carbamic acid benzyl ester

1,3-dibenzylurea

methyl N-benzylcarbamate

N-(dimethylcarbamoyl)benzylamine

Refernces

• 1、 Ying, Hanze,Yang, Yingfeng,Cai, Kaimin,Cheng, Jianjun. "Hindered urea bond: A bilaterally responsive chemistry to hydrogen peroxide". supporting information. p. 728 - 731. Retrieved 2019/01/24.
• 2、 Ghodsinia, Sara S.E.,Akhlaghinia, Batool. "A high-yielding, expeditious, and multicomponent synthesis of urea and carbamate derivatives by using triphenylphosphine/trichloroisocyanuric acid system". . p. 104 - 110. Retrieved 2016/01/25.